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Measurement of the coefficient of translational diffusion in liquid solutions by means of EPR

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Abstract

A new method of diffusion coefficient measurement in liquids under electrolysis is considered. It is shown that the diffusion parameters can be correctly determined from the dependence on the electrolysis time of the EPR signal intensity of the ion radicals formed.

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Authors and Affiliations

  1. Institute of Organic and Physical Chemistry, Arbuzov str. 8, 420083, Kazan, USSR

    A. V. Il’yasov & V. V. Yanilkin

  2. Bruker Analytische Messtechnik GmbH, Rheinstetten, FRG

    U. Eichhoff

Authors
  1. A. V. Il’yasov
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  2. M. K. Kadirov
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  3. Yu. M. Kargin
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  4. V. V. Yanilkin
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  5. U. Eichhoff
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Il’yasov, A.V., Kadirov, M.K., Kargin, Y.M. et al. Measurement of the coefficient of translational diffusion in liquid solutions by means of EPR. Appl Magn Reson 1, 92–96 (1990). https://doi.org/10.1007/BF03166012

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  • DOI: https://doi.org/10.1007/BF03166012

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