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Xenon matrix and zeolite Na-Y two methods for study of radical cations

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Abstract

Two new methods for the study of reactive radical cations are outlined. The commonly used freon matrix method for the study of radical cations produced by the γ- radiolysis is augmented by the use of a xenon matrix with an electron scavenger. The use of a zeolite matrix is a new development as the zeolite structure, and the ions in the zeolite can be utilized to stabilize radiolytically produced cations in a remarkable temperature range.

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Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE under contract number W-31-109-ENG-38.

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Trifunac, A.D., Qin, X.Z. Xenon matrix and zeolite Na-Y two methods for study of radical cations. Appl Magn Reson 1, 29–40 (1990). https://doi.org/10.1007/BF03166006

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