Abstract
Xenon-129 NMR spectra have been measured for solutions containing Xe dissolved in a variety of linear 1-haloalkanes, α, ω-dihaloalkanes, and their mixtures. The data are found to be linearly related to solvent composition expressed as volume fraction of the constituent methyl groups, methylene groups, and halogen atoms. This behavior is consistent with a model in which the large dispersion force contributions to the chemical shift of129Xe result from pair interactions between dissolved Xe atoms and the methyl, and methylene groups, and the halogen atom, from which the solvent molecules are composed.
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Stephen M.J.: Mol. Phys.1, 223–232 (1958)
Buckingham A.D., Schaefer T., Schneider W.G.: J. Chem. Phys.32, 1227–1233 (1960)
Homer J. in: Applied Spectroscopy Reviews (Brame E.G., Jr., ed.), vol. 9, pp. 1–132. New York: Marcel Dekker 1975; b) Rummens F.H.A. in: NMR, Basic Principles and Progress (Diehl P., Fluck E., Kosfeld R., eds.), vol. 10. pp. 1–118. Heidelberg: Springer-Verlag 1975; c) Riesse J.: Nouv. J. Chim.10, 665–672 (1986); d) Dybowski C., Bansal N., Duncan T.M.: Ann. Rev. Phys. Chem.42, 433–464 (1991); e) Barrie P.J., Klinowski J.: Progress in NMR Spectroscopy24, 91–108 (1992); f) Jokasaari J.: Progress in NMR Spectroscopy26, 1–26 (1994); g) Bishop D.M.: Int. Rev. Phys. Chem.13, 21–39 (1994)
Lim Y.-H., Nugara N.E., King A.D. Jr.: J. Phys. Chem.97, 8816–8819 (1993)
Rummens F.H.A., Raynes W.T., Bernstein H.J.: J. Phys. Chem.72, 2111–2119 (1968)
Lim Y.-H., King A.D. Jr.: J. Phys. Chem.97, 12173–12177 (1993)
Lim Y.-H., Nugara N., King A.D. Jr.: Appl. Magn. Reson.8, 521–534 (1995)
Hildebrand J.H., Prausnitz J.M., Scott R.L.: Regular and Related Solutions. New York: Van Nostrand Reinhold 1970.
Lim, Y.-H.: Ph.D. Dissertation. University of Georgia 1991.
Lim Y.-H.: M.S. Thesis. University of Georgia 1989.
Dreisbach R.R.: Physical Properties of Chemical Compounds III, Advances in Chemistry Series 29. Washington: American Chemical Society 1961.
Landolt H.A., Börnstein R.: Zahlenwerte und Functionen, 6th edition (Hellwege K.H., Hellwege A.M., eds.), vol. 2, pt. 10. Berlin: Springer-Verlag 1967.
Khama N.: J. Sci. Ind. Res. (India)6B, 10–15 (1947)
Haberditzl W.: Angew. Chem., Int. Ed.5, 288–298 (1966)
Miller K.W., Reo N.V., Schoot Uiterkamp A.J.M., Stengle D.P., Stengle T.R., Williamson K.L.: Proc. Natl. Acad Sci. USA78, 4946–4949 (1981)
Stengle T.R., Reo N.V., Williamson K.L.: J. Phys. Chem.85, 3772–3775 (1981)
Diehl P., Ugolini R., Suryaprakash N., Jokisaari J.: Magn. Reson. Chem.29, 1163–1164 (1991)
Jameson C.J., de Dios A.C.: J. Chem. Phys.97, 417–434 (1992)
Howard B.B., Linder B., Emerson M.T.: J. Chem. Phys.36, 485–490 (1962)
Rummens F.: Chem. Phys. Lett.31, 596–598 (1975)
Beilstein F.K.: Handbuch der Organischen Chemie, Erster, Band, Erster Teil, 4th Supplement. Berlin: Springer Verlag 1972.
Stengle T.R., Williamson K.L.: Macromolecules20, 1428–1430 (1987)
Bryant W.M.D.: J. Polymer Sci.2, 547–564 (1947)
Raynes W.T.: J. Chem. Phys.51, 3138–3140 (1969)
Exner O.: Collection Czechoslov. Chem. Commun.32, 1–23 (1966)
Partington J.R.: An Advanced Treatise on Physical Chemistry, vol. 4. London: Longmans, Green and Co. 1953.
Broersma S.: J. Chem. Phys.17, 873–882 (1949)
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Lim, Y.H., Calhoun, A.R. & King, A.D. NMR chemical shifts of129Xe dissolved in liquid haloalkanes and their mixtures. Appl. Magn. Reson. 12, 555–574 (1997). https://doi.org/10.1007/BF03164135
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DOI: https://doi.org/10.1007/BF03164135