Abstract
The RF losses in NMR experiments on ionic solutions have been investigated by multi-NMR. The change of π/2 pulse length (PW)90 for23Na,35Cl,2D,17O and1H nuclei in NaCl/D2O solutions has been systematically studied. Quantitative relation between (PW)90 values and the sample specific conductivity σ has been established. The increase in (PW)90 values has been experimentally correlated to the reduction of the signal-to-noise ratio through17O measurements.
Similar content being viewed by others
References
Ernst R.R., Bodenhausen G., Wokaun A.: Principles of Nuclear Magnetic Resonance in One and Two Dimensions, p. 135. Oxford: Clarendon 1987.
Bock K., Meyer B., Vignon M.: J. Magn. Reson.38, 545–511 (1980)
Brown R.W., Haacke E.M., Martens M.A., Patrick J.L., Zypman F.R.: J. Magn. Reson.80, 225–247 (1988)
Hoult D.I., Lauterbur P.C.: J. Magn. Reson.34, 425–433 (1979)
Gadian D.G., Robinson F.N.H.: J. Magn. Reson.34, 449–455 (1979)
Carlson J.W.: J. Magn. Reson.78, 563–573 (1988)
Glover G.H., Hayes C.E., Pelc N.J., Edelstein W.A., Mueller O.M., Hart H.R., Hardy C.J., O’Donnell M., Barber W.D.: J. Magn. Reson.64, 255–270 (1985)
Robinson M.A.: J. Magn. Reson.95, 574–580 (1991)
Von Hippel A. in: Handbook of Physics, 2nd ed. (Condon E.U., Odishaw H., eds.), Part 4, Chap. 7. New-York: McGraw-Hill 1967.
Kong J.A.: Theory of Electromagnetic Waves, p. 13, New York: Wiley 1975.
Winsor P., Cole R.H.: J. Phys. Chem.89, 3775–3776 (1985)
Kaatze U.: J. Phys. Chem.91, 3111–3113 (1987)
Horvath A.L.: Handbook of Aqueous Electrolyte Solutions. New York: Wiley 1985 and references therein.
La Mer V.K.: Chem. Rev.19, 363–374 (1936)
Hetland E.: J. Am. Chem. Soc.68, 2532–2535 (1946)
Lukashov Yu.M., Savenko V.V.: Zh. Fiz. Khim.54, 1582–1585 (1980)
Hoult D.I., Richards R.E.: J. Magn. Reson.24, 71–85 (1976)
Shaw D.: Fourier Transform NMR Spectroscopy, p. 166, Amsterdam: Elsevier 1976.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mao, X.A., Holz, M. Multinuclear study of RF losses in NaCl/D2O solutions. Appl. Magn. Reson. 6, 529–536 (1994). https://doi.org/10.1007/BF03162642
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03162642