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Comparative analysis of pulsed electron spin resonance spectrometers at X-band and S-band

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Abstract

Comparative analysis of pulsed electron spin resonance spectroscopy at X-band and at S-band indicates that despite the lower sensitivity at the lower frequency, electron spin echo spectroscopy at S-band provides valuable information on the electron-nuclear interactions in systems where the electron spin echo modulation is too small to study well at X-band. It is shown that independent experimental data on electron spin echo modulation and decay at both X-band and S-band put additional constraints on the structural parameters obtained by comparison of experimental and simulated nuclear modulation patterns, and can also help to elucidate the electron spin relaxation mechanism.

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Author notes

  1. V. Kurshev

    Present address: Institute of Chemical Kinetics and Combustion, 630090, Novosibirsk, Russia

Authors and Affiliations

  1. Department of Chemistry, University of Florence, Florence, Italy

    M. Romanelli

  2. Department of Chemistry, University of Houston, 77204-5641, Houston, TX, USA

    V. Kurshev & L. Kevan

Authors
  1. M. Romanelli
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  2. V. Kurshev
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  3. L. Kevan
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Romanelli, M., Kurshev, V. & Kevan, L. Comparative analysis of pulsed electron spin resonance spectrometers at X-band and S-band. Appl. Magn. Reson. 7, 427–441 (1994). https://doi.org/10.1007/BF03162623

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  • DOI: https://doi.org/10.1007/BF03162623

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