Abstract
We analyze the electron paramagnetic resonance linewidth in Rb2Pt(CN)4(FHF)0.4 as a function of temperature. Above 60 K, the results are interpreted as a superposition of spin-phonon and spin-spin relaxation effects. The dominant contribution to the relaxation rate l/T2 has a dipolar origin in contrast to the spin-phonon origin observed in K2Pt(CN)4Br0.3 · H2O. This difference could arise from different anisotropy ratios of the transfer integrals. The influence of the interchain coupling is also discussed.
Similar content being viewed by others
References
Krogmann K.: Angew. Chem. Int. Ed. Engl.8, 35–42 (1969)
Toombs G.A.: Phys. Rep.40, 181–240 (1978)
Mehran F., Scott B.A.: Phys. Rev. Lett.31, 1347–1349 (1973)
Takahashi T., Doi H., Nagasawa H.: J. Phys. Soc. Jpn.48, 423–429 (1980)
Pană O., Giurgiu L.V., Mehring M.: Solid State Commun.84, 651–655 (1992)
Pană O., Kessler C., Filip C., Giurgiu L.V., Ursu I., Mehring M.: Appl. Magn. Reson.12, 247–253 (1997)
Mehring M., Deininghaus U., Fischer H., Seidel H., Weber H. in: New Techniques and Applications of Magnetic Resonance, Proceedings of the 7th AMPERE International Summer School, Portoroz, Slovenia (Blinc R., Vilfan M., eds.), pp. 211–233. Ljubljana: J. Stefan Institute 1982; Mehring M., Kanert O., Mali M., Brinkmann D.: Solid State Commun.33, 225–228 (1980)
Coffey C.C., Williams J.M.: Inorg. Synth.20, 25–26 (1979)
Poole C.P. Jr.: Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques, 2nd edn., p. 592. New York: John Wiley & Sons 1983.
Tomkiewicz Y., Taranko A.R.: Phys. Rev. B18, 733–742 (1978)
Elliot R.J.: Phys. Rev.96, 266–279 (1954)
Hennessy M.J., McElwee C.D., Richards P.M.: Phys. Rev. B7, 930–947 (1973)
Wood D.J., Underhill A.E., Schultz A.J., Williams J.M.: Solid State Commun.30, 501–504 (1979)
Soda G., Jérome D., Weger M., Alizon J., Gallice J., Robert H., Fabre J.M., Giral L.: J. Phys.38, 933–948 (1977)
Carneiro K., Petersen A.S., Underhill A.E., Wood D.J., Watkins D.M., Mackenzie G.A.: Phys. Rev. B19, 6279–6288 (1979)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Knorr, S., Filip, X., Darabont, A. et al. Spin relaxation in the quasi-one-dimensional conductor Rb2Pt(CN)4(FHF)0.4 . Appl. Magn. Reson. 19, 373–379 (2000). https://doi.org/10.1007/BF03162379
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF03162379