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Spin relaxation in the quasi-one-dimensional conductor Rb2Pt(CN)4(FHF)0.4

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Abstract

We analyze the electron paramagnetic resonance linewidth in Rb2Pt(CN)4(FHF)0.4 as a function of temperature. Above 60 K, the results are interpreted as a superposition of spin-phonon and spin-spin relaxation effects. The dominant contribution to the relaxation rate l/T2 has a dipolar origin in contrast to the spin-phonon origin observed in K2Pt(CN)4Br0.3 · H2O. This difference could arise from different anisotropy ratios of the transfer integrals. The influence of the interchain coupling is also discussed.

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References

  1. Krogmann K.: Angew. Chem. Int. Ed. Engl.8, 35–42 (1969)

    Article  Google Scholar 

  2. Toombs G.A.: Phys. Rep.40, 181–240 (1978)

    Article  ADS  Google Scholar 

  3. Mehran F., Scott B.A.: Phys. Rev. Lett.31, 1347–1349 (1973)

    Article  ADS  Google Scholar 

  4. Takahashi T., Doi H., Nagasawa H.: J. Phys. Soc. Jpn.48, 423–429 (1980)

    Article  ADS  Google Scholar 

  5. Pană O., Giurgiu L.V., Mehring M.: Solid State Commun.84, 651–655 (1992)

    Article  ADS  Google Scholar 

  6. Pană O., Kessler C., Filip C., Giurgiu L.V., Ursu I., Mehring M.: Appl. Magn. Reson.12, 247–253 (1997)

    Article  Google Scholar 

  7. Mehring M., Deininghaus U., Fischer H., Seidel H., Weber H. in: New Techniques and Applications of Magnetic Resonance, Proceedings of the 7th AMPERE International Summer School, Portoroz, Slovenia (Blinc R., Vilfan M., eds.), pp. 211–233. Ljubljana: J. Stefan Institute 1982; Mehring M., Kanert O., Mali M., Brinkmann D.: Solid State Commun.33, 225–228 (1980)

    Google Scholar 

  8. Coffey C.C., Williams J.M.: Inorg. Synth.20, 25–26 (1979)

    Google Scholar 

  9. Poole C.P. Jr.: Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques, 2nd edn., p. 592. New York: John Wiley & Sons 1983.

    Google Scholar 

  10. Tomkiewicz Y., Taranko A.R.: Phys. Rev. B18, 733–742 (1978)

    Article  ADS  Google Scholar 

  11. Elliot R.J.: Phys. Rev.96, 266–279 (1954)

    Article  ADS  Google Scholar 

  12. Hennessy M.J., McElwee C.D., Richards P.M.: Phys. Rev. B7, 930–947 (1973)

    Article  ADS  Google Scholar 

  13. Wood D.J., Underhill A.E., Schultz A.J., Williams J.M.: Solid State Commun.30, 501–504 (1979)

    Article  ADS  Google Scholar 

  14. Soda G., Jérome D., Weger M., Alizon J., Gallice J., Robert H., Fabre J.M., Giral L.: J. Phys.38, 933–948 (1977)

    Google Scholar 

  15. Carneiro K., Petersen A.S., Underhill A.E., Wood D.J., Watkins D.M., Mackenzie G.A.: Phys. Rev. B19, 6279–6288 (1979)

    Article  ADS  Google Scholar 

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Knorr, S., Filip, X., Darabont, A. et al. Spin relaxation in the quasi-one-dimensional conductor Rb2Pt(CN)4(FHF)0.4 . Appl. Magn. Reson. 19, 373–379 (2000). https://doi.org/10.1007/BF03162379

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  • DOI: https://doi.org/10.1007/BF03162379

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