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Offset dependence of homonuclear hartmann-hahn transfer based on residual dipolar couplings in solution state NMR

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Abstract

The offset dependence of homonuclear Hartmann-Hahn transfer is markedly different if a given multiple-pulse sequence is applied to dipolar coupled spins or to isotropically coupled spins. The different offset dependence of the transfer efficiency is studied by numerical simulations of a multiple-pulse sequence and by the analytical treatment of a simple model experiment.

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Authors and Affiliations

  1. Institut für Organische Chemie und Biochemie, Technische Universität München, Garching, Germany

    F. Kramer & S. J. Glaser

  2. Institut für Organische Chemie, J.W. Goethe-Universität, Frankfurt, Germany

    B. Luy

Authors
  1. F. Kramer
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  2. B. Luy
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  3. S. J. Glaser
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Kramer, F., Luy, B. & Glaser, S.J. Offset dependence of homonuclear hartmann-hahn transfer based on residual dipolar couplings in solution state NMR. Appl. Magn. Reson. 17, 173–187 (1999). https://doi.org/10.1007/BF03162159

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  • DOI: https://doi.org/10.1007/BF03162159

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