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Solvent-induced H/D isotope effect on129Xe chemical shifts

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Abstract

An effect of substitution of deuterium for protium in molecules of 17 solvents onl29Xe NMR shifts was studied. The variation range of solvent-induced isotope xenon shifts σ is exceeds 5 ppm and lies in the range from −1.18 ppm (in CH3OD solution) to 3.92 ppm (in D2O) at 28°C. Experimental results agree with the concept that interaction of xenon atoms with solvent molecules is determined predominantly by dispersion forces. Correlations of σ is with the isotope effect on polarizability, boiling point, and vapor pressure of solvents were established. Anomalous manifestation of properties of aqueous solution was detected.

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References

  1. Miller K.W., Reo N.V., Uiterkamp A.J.M.S., Stengle D.P., Stengle T.R., Williamson K.L.: Proc. Natl. Acad.Sci. USA78, 4946–4949 (1981)

    Article  ADS  Google Scholar 

  2. Stengle T.R., Reo N.V., Williamson K.L.: J. Phys. Chem.85, 3772–3775 (1981)

    Article  Google Scholar 

  3. Stengle T.R., Hosseini S.M., Basiri H.G., Williamson K.L.: J. Sol. Chem.13, 779–787 (1984)

    Article  Google Scholar 

  4. Stengle T.R., Williamson K.L.: Macromolecules20, 1428–1430 (1987)

    Article  ADS  Google Scholar 

  5. Lim Y.-H., Nugura N., King A.D. Jr.: J. Phys. Chem.97, 8816–8819 (1993)

    Article  Google Scholar 

  6. Lim Y.-H., King A.D. Jr.: J. Phys. Chem.97, 12173–12177 (1993)

    Article  Google Scholar 

  7. Miller J.B., Walton J.H., Roland C.M.: Macromolecules26, 5602–5610 (1993)

    Article  ADS  Google Scholar 

  8. Lim Y.-H., Nugura N., King A.D. Jr.: Appl. Magn. Reson.8, 521–534 (1995)

    Article  Google Scholar 

  9. Walton J.H., Miller J.B., Roland C.M.: Appl. Magn. Reson.8, 535–547 (1995)

    Article  Google Scholar 

  10. Rummens F.H.A.: NMR Basic Principles and Progress, vol. 10, pp. 1–118. New York: Springer 1975.

    Google Scholar 

  11. Homer J.: Applied Spectroscopy Reviews, vol. 9, pp 1–132. New York: Marcel Dekker 1975.

    Google Scholar 

  12. Seydoux R., Diehl P., Mazitov R.K., Jokisaari J.: J. Magn. Reson. Ser. A101, 78–83 (1993)

    Article  Google Scholar 

  13. Bazhenov D.V., Grishin Yu.K., Ustinyuk Yu.A.: Metalloorganich. Khim. (in Russian)5, 297–330 (1992)

    Google Scholar 

  14. Mazitov R.K., Diehl P., Rotter G., Garanin W.V.: Rev. Sci. Instrum.65, 2149–2150 (1994)

    Article  ADS  Google Scholar 

  15. Buckingham A.D., Schaefer T., Schneider W.G.: J. Chem. Phys.32, 1227–1233 (1960)

    Article  ADS  Google Scholar 

  16. Ergin Yu.B.: Magnetic Properties and Structure of Electrolyte Solutions (in Russian). Moscow: Nauka 1983.

    Google Scholar 

  17. Mazitov R.K., Enikeev K.M., Ilyasov A.V.: Radiospektroscopiya (in Russian) (Shaposhnikov I.G., ed.), pp. 106–116. Perm: Perm University Press 1988.

    Google Scholar 

  18. Stephen M.J.: Mol. Phys.1, 223–232 (1958)

    Article  ADS  Google Scholar 

  19. McRae E.J.: J. Phys. Chem.61, 562–572 (1957)

    Article  Google Scholar 

  20. Reichardt C.: Solvents and Solvent Effects in Organic Chemistry. Weinheim: VCH 1988.

    Google Scholar 

  21. Raynes W.T., Buckingham A.D., Bernstein H.J.: J. Chem. Phys.36, 3481–3488 (1962)

    Article  ADS  Google Scholar 

  22. Rabinovich I.B.: Influence of Isotopic Substitution on Physical-Chemistry Properties of Liquids (in Russian). Moscow: Nauka 1968.

    Google Scholar 

  23. Baertschi P., Kuhn W.: Helv. Chim. Acta40, 1084–1103 (1957)

    Article  Google Scholar 

  24. Hildebrand J.H., Prausnitz J.M., Scott R.L.: Regular and Related Solutions. Princeton: Van Nostrand-Reinhold 1970.

    Google Scholar 

  25. Barton A.F.M.: Chem. Rev.75, 731–753 (1975)

    Article  Google Scholar 

  26. Kamlet M.J., Taft R.W.: Acta Chem. Scand. B39, 611–628 (1985)

    Article  Google Scholar 

  27. Hildebrand J.H., Scott R.L.: Solubility of Non-Electrolytes, p. 427. New-York: Rein-Publishing Corp. 1950.

    Google Scholar 

  28. Catalog Handbook of Fine Chemicals. Milwaukee: Aldrich Chemical Company 1994–1995.

  29. Frontasyev V.P., Shraiber L.S.: Zhurn. Struct. Khim. (in Russian)6, 512–521 (1965)

    Google Scholar 

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Authors and Affiliations

  1. NMR Laboratory, Chemistry Department, Moscow State University, Moscow, Russian Federation

    Yu. K. Grishin

  2. Institute of General and Inorganic Chemistry, Moscow, Russian Federation

    R. K. Mazitov & A. N. Panov

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospect 31, 117907, Moscow, Russian Federation

    R. K. Mazitov

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  1. Yu. K. Grishin
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  2. R. K. Mazitov
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  3. A. N. Panov
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Grishin, Y.K., Mazitov, R.K. & Panov, A.N. Solvent-induced H/D isotope effect on129Xe chemical shifts. Appl. Magn. Reson. 14, 357–366 (1998). https://doi.org/10.1007/BF03161901

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  • DOI: https://doi.org/10.1007/BF03161901

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