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ESR study of some iminoxy free radicals generated from phosphorylated oximes and dioximes

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Abstract

The new type of phosphoniminoxy free radicals was generated electrochemically or by chemical oxidation of oximes. It was established the strong difference of ESR parameters for isomeric Z and E forms of the radicals. The spin distribution and its correlation with electronic and spatial characteristics of molecules as well as with intramolecular interactions are discussed.

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Authors and Affiliations

  1. Arbusov Institute of Organic and Physical Chemisry, Kazan, Russian Federation

    A. V. Il’yasov & A. A. Vafina

  2. Department of Pharmaceutical Chemistry, Hebrew University of Jerusalem, Jerusalem, Israel

    E. Breuer

  3. Institute of Inorganic and Structure Chemistry, Heinrich-Heine-University of Düsseldorf, Düsseldorf, Germany

    G. Hägele

Authors
  1. A. V. Il’yasov
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  2. A. A. Vafina
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  3. E. Breuer
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  4. G. Hägele
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Il’yasov, A.V., Vafina, A.A., Breuer, E. et al. ESR study of some iminoxy free radicals generated from phosphorylated oximes and dioximes. Appl. Magn. Reson. 14, 489–496 (1998). https://doi.org/10.1007/BF03161857

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  • DOI: https://doi.org/10.1007/BF03161857

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