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Some peculiarities of spin-lattice relaxation of impurity rare-earth ions in crystals caused by the structure defects

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Abstract

The spin-lattice relaxation times for Nd3+ ions in yttrium-aluminum garnets (YAG) and for Yb3+ ions in CaF2 in the low-temperature range have been measured. For the first system the temperature dependence of the relaxation rate is determined to a great extent by the method of sample preparation. For samples grow by the method of the horizontally oriented crystallization the dependence is described asT −11 =AT n,n ≅ 4.7, which is an evidence of an influence of local structure disordering on the relaxation. The temperature dependence of the relaxation rate in CaF2:Yb is also “anomalous”:T −11 =AT 3.3. The results are compared with the previous data on the relaxation in similar systems, and with other cases of observation of “anomalous” temperature dependences. Different manifestations of the local crystal defects in spin-lattice relaxation are discussed.

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References

  1. Al’tshuler S.A., Kozyrev B.M.: Elektronnii Paramagnitnii Rezonans Soedinenii Elementov Promezhutochnikh Grupp. Moscow: Nauka 1972.

    Google Scholar 

  2. Van Vleck J.H.: Phys. Rev.57, 426 (1940)

    Article  ADS  Google Scholar 

  3. Aminov L.K., Kurkin I.N.: Fiz. Tverd. Tela37, 2684 (1995)

    Google Scholar 

  4. Korolev V.D., Peskovatskii S.A., Shulga V.M.: Phys. Status Solidi B93, K45 (1979)

    Article  Google Scholar 

  5. Stevens S.B., Stapleton H.J.: Phys. Rev. B42, 9794 (1990)

    Article  ADS  Google Scholar 

  6. Parshin D.A.: Fiz. Tverd. Tela36, 1809 (1994)

    Google Scholar 

  7. Askew T.R., Stapleton H.J., Brower K.L.: Phys. Rev. B33, 4455 (1986)

    Article  ADS  Google Scholar 

  8. Deville A., Gaillard B., Blanchard C., Livage J.: J. Phys.44, 77 (1983)

    Google Scholar 

  9. Nikolova E.P., Timan B.L.: Zh. Prikl. Spektrosk.36, 479 (1982)

    Google Scholar 

  10. Hayes W., Twidell J.W.: J. Chem. Phys.35, 1521 (1961)

    Article  ADS  Google Scholar 

  11. Bagdasarov Kh.S., Daraseliya D.M., Manenkov A.A.: Pis’ma Zh. Eksp. Teor. Fiz.8, 529 (1965)

    Google Scholar 

  12. Huang C.Y.: Phys. Rev.139, A241 (1965)

    Article  ADS  Google Scholar 

  13. Autipin A.A., Katyshev A.N., Kurkin I.N., Shekun L.Ya.: Fiz. Tverd. Tela9, 3400 (1967)

    Google Scholar 

  14. Bierig R.W., Weber M.J., Warshaw S.I.: Phys. Rev.134, A1504 (1964)

    Article  ADS  Google Scholar 

  15. Kaminskii A.A.: Lazernie Kristalli. Moscow: Nauka 1975.

    Google Scholar 

  16. Aminov L.K., Tagirov M.S., Teplov M.A.: Zh. Eksp. Teor. Fiz.79, 1322 (1980)

    Google Scholar 

  17. Aminov L.K., Kurkin I.N., Kurzin S.P., Lukoyanov D.A., Salikhov I.Kh., Rakhmatullin R.M.: Zh. Eksp. Teor. Fiz.111, 332 (1997)

    Google Scholar 

  18. Aminov L.K., Vinokurov A.V., Kurkin I.N., Kostetskii Yu.Yu., Korableva S.L., Salikhov I.Kh., Sakhaeva S.I., Teplov M.A.: Phys. Status Solidi B152, 191 (1989)

    Article  Google Scholar 

  19. Shanina B.D., Semenov Yu.G.: Fiz. Tverd. Tela16, 1911 (1974)

    Google Scholar 

  20. Rebane K.K.: Elementarnaya Teoriya Kolebatel’noi Strukturi Spektrov Primesnikh Centrov Kristallov. Moscow: Nauka 1968.

    Google Scholar 

  21. Gracheva T.V., Merkulyaeva T.I., Petrova M.A., Podkolzina I.G., Semenova T.S., Koryakina L.F. in: Tezisi 8-go Vsesoiuznogo Simpoziuma po Khimii Neorganicheskikh Ftoridov. Polevskoi (August 22–27, 1987), p. 115.

  22. Ashurov M.Kh., Voron’ko Yu.K., Osiko V.V., Sobol’ A.A. in: Spektroskopiya Kristallov, p. 71. Leningrad: Nauka 1978.

    Google Scholar 

  23. Maradudin A.A.: Solid State Physics (Seitz F., Turnbull D., eds.), vols. 18 and 19. New York: Academic Press 1966.

    Google Scholar 

  24. Kurtz S.R., Stapleton H.J.: Phys. Rev. B22, 2195 (1980)

    Article  ADS  Google Scholar 

  25. Aminov L.K., Kurkin I.N., Lukoyanov D.A., Chernov K.P.: Fiz. Tverd. Tela39, 1335–1337 (1997)

    Google Scholar 

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Aminov, L.K., Kurkin, I.N. & Lukoyanov, D.A. Some peculiarities of spin-lattice relaxation of impurity rare-earth ions in crystals caused by the structure defects. Appl. Magn. Reson. 14, 447–456 (1998). https://doi.org/10.1007/BF03161854

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