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Determination of the polarizability and the dipole moment of anthracene derivatives

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Acta Physica Academiae Scientiarum Hungaricae

Abstract

The difference of dipole moments between the excited and ground state was determined to be 1.9 and 1.8 Debye for 9-acetoxyanthracene and 10-phenyl-9-acetoxyanthracene from the frequency shifts of absorption and emission spectra. The polarizability of these two compounds is 36×10−24 and 54×10−24 cm3, respectively. The measured natural lifetimes are compared with those calculated from the absorption integral taking into account the effect of intermolecular interactions on the optical properties of dissolved molecules.

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References

  1. J. A. Myer, C. L. Johnson, E. Kierstead, R. D. Sharmo andI. Itzka, Appl. Phys. Letters,15, 3, 1970.

    Article  ADS  Google Scholar 

  2. J. Ferguson andA. W. H. Mau, Chem. Phys. Letters,14, 245, 1972.

    Article  ADS  Google Scholar 

  3. F. P. Schäfer, Topics in Applied Physics, Vol. 1. Springer-Verlag, Heidelberg, 1973.

    Google Scholar 

  4. J. R. Heldt, J. Gronowska andJ. Heldt, Acta Phys. Polon,A 47, 613, 1974.

    Google Scholar 

  5. Janina Heldt andJ. Heldt, Acta Phys. Polon.,A55, 79, 1979.

    Google Scholar 

  6. Janina Heldt, Józef Heldt andJanina Gronowska, Z. f. Naturforschg.,30a, 612, 1975.

    ADS  Google Scholar 

  7. N. S. Bayliss, J. Chem. Phys.,18, 292, 1950.

    Article  ADS  Google Scholar 

  8. Y. Ooshika, J. Chys. Soc. Japan,9, 594, 1954.

    Article  ADS  Google Scholar 

  9. E. Lippert, Z. Elektrochem,61, 962, 1957.

    Google Scholar 

  10. L. Bilot andA. Kawski, Z. f. Naturforschg.,17a, 621, 1962.

    ADS  Google Scholar 

  11. W. Liptay, Z. f. Naturforschg.,20, 1441, 1965.

    ADS  Google Scholar 

  12. N. Mataga, Y. Kaifu andM. Koizumi, Bull. Chem. Soc. Japan,29, 465, 1956.

    Article  Google Scholar 

  13. N. Mataga andT. Kubota, Molecular Interactions and Electronic Spectra, New York, Dekker, 1970.

  14. I. Schuyer, Rec. Trav. Chim.,72, 933, 1953.

    Google Scholar 

  15. B. S. Neporent andN. G. Bakhshiev, Optik i Spektrosk.,5, 634, 1958.

    Google Scholar 

  16. H. Onsager, J. Amer. Chem. Soc.,58, 1986, 1936.

    Article  Google Scholar 

  17. R. K. Bauer andA. Kowalczyk, Raport techniczny Nr 3, Nicholas Copernicus University, Torun, 1974.

  18. Technique of Organic Chemistry, Arnold Wiessberger, Editor Vol. VII, Interscience Publishers Inc., New York, 1956.

  19. B. Pasztor-Bartoszewicz, Zeszyty Naukowe, WSP Gdansk,8, 55, 1968.

    Google Scholar 

  20. W. Liptay, G. Walz, W. Baumann, H. J. Schlosser, H. Deckers andN. Detzer, Z. Naturforsch.,26a, 2020, 1971.

    ADS  Google Scholar 

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This work was carried on under the Research Project 10.2

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Heldt, J., Heldt, J. Determination of the polarizability and the dipole moment of anthracene derivatives. Acta Physica 46, 185–191 (1979). https://doi.org/10.1007/BF03159430

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  • DOI: https://doi.org/10.1007/BF03159430

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