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Investigation of theA 3п state of the NH molecule

Исследование состоянияA 3П молекулы NH

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Acta Physica Academiae Scientiarum Hungaricae

Abstract

The multiplet splittings observed in theA 3π state of the NH molecule, as a function of the rotational quantum number, deviate from the formulas derived on the basis ofVan Vleck’s theory, can well be interpreted — in good agreement with the measuring results — as the perturbation of the3π state by the1π state as well as by taking into account simultaneously the spin-spin interaction.

Резюме

Мультиплетные расщелления, наблюдаемые в состоянииA 3П молекулы NH в зависимости от ротационоого квантового числа отличаются от формул, выведенных на основе теории Ван Флека. Их интерпретация возможна возмущением, вызванным в состоянии3П состоянием1П, а также одновременным учетом спин-спинового взаимодействия, причем получается хорошее совпадение с результатами измерений.

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Additional information

A report of this work was given at the Seminary on Molecular Spectroscopy, University of Liège, Belgium, 25th May, 1960.

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Kovács, I. Investigation of theA 3п state of the NH molecule. Acta Physica 12, 67–76 (1960). https://doi.org/10.1007/BF03157695

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  • DOI: https://doi.org/10.1007/BF03157695

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