Abstract
The mean amplitudes of vibration for five isotope-substituted difluoro-phosphine-boranes F2XP·BX3 (X=H, D; B=11B,10B), have been calculated on the basis of structural and spectroscopic data from the literature. Potential barriers to internal rotation have also been determined from torsional frequencies, from calculated mean-square amplitudes of vibration and from mean torsional angle differences. Results obtained for various phosphine-boranes are compared.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R.W. Rudolph and R.W. Parry, J. Am. Chem. Soc.,89, 1621, 1967.
J.R. Durig, Y.S. Li, L.A. Carreira and J.D. Odom, J. Am. Chem. Soc.,95, 2491, 1973.
R.L. Kuczkowski and D.R. Lide, J. Chem. Phys.,46, 357, 1967.
J. Pasinski and R.L. Kuczkowski, J. Chem. Phys.,54, 1903, 1971.
R.C. Taylor and V.D. Dunning, J. Mol. Struct.,95, 23, 1982.
A. Sebestyén, L. Megyeri and B. Vizi, J. Mol. Struct., THEOCHEM,89, 259, 1982.
A. Sebestyén, Per. Polytechn. Chem. Eng.,30, 205, 1986.
B. Gellai, J. Mol. Struct.,42, 181, 1977.
S.J. Cyvin, Molecular Vibration and Mean Square Amplitudes, Elsevier, Oslo 1968.
M. Hargittai and I. Hargittai, A kémia újabb eredményei, 23, Akadémiai Kiadó, Budapest, 1974.
L.V. Vilkov, N.A. Penionzhkevich, J. Brunvoll and I. Hargittai, J. Mol. Struct.,43, 109, 1978.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sebestyén, A. Vibrational spectroscopic calculations on difluoro-phosphine-borane and its isotopesubstituted derivatives (F2XP·BX3, X=H, D; B11B,10B). Acta Physica Hungarica 63, 151–154 (1988). https://doi.org/10.1007/BF03155766
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03155766