Skip to main content
SpringerLink
Log in

An evaluation of the kinetic data for hydrogen abstraction from silanes in the gas phase

  • Published:
Reviews of Chemical Intermediates Aims and scope Submit manuscript

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. A.F. Trotman-Dickenson and G.S. Milne, “Tables of Bimolecular Gas Reactions,” NSRDS-NBS,9 (1967).

  2. E. Ratajczak and A.F. Trotman-Dickenson, “Supplementary Tables of Bimolecular Gas Reactions,” University of Wales Institute of Science and Technology Cardiff, 1969.

    Google Scholar 

  3. J. A. Kerr and E. Ratajczak, “Second Supplementary Tables of Bimolecular Gas Reactions,” The University of Birmingham, Birmingham, 1972.

    Google Scholar 

  4. P. Gray, A. A. Herod, and A. Jones,Chem. Rev.,71, 247 (1971).

    Article  Google Scholar 

  5. J. A. Kerr and M. J. Parsonage, “Evaluated Kinetic Data on Gas Phase Hydrogen Transfer Reactions of Methyl Radicals,” Butterworths, London, Boston, 1976.

    Google Scholar 

  6. I. M. T. Davidson,Quart. Rev., Chem. Soc.,25, 111 (1971).

    Article  CAS  Google Scholar 

  7. I. M. T. Davidson,Specialist Periodical Reports, Chem. Soc., Reaction Kinetics,1, 212 (1975).

    CAS  Google Scholar 

  8. H. Niki and G. J. Mains,J. Phys. Chem.,68, 304 (1964).

    Article  CAS  Google Scholar 

  9. M. A. Nay, G. N. C. Woodall, O. P. Strausz, and H. E. Gunning,J. Am. Chem. Soc.,87, 179 (1965).

    Article  CAS  Google Scholar 

  10. E. Kamaratos and F. W. Lampe,J. Phys. Chem.,74, 2267 (1970).

    Article  CAS  Google Scholar 

  11. A. G. Alexander, O. P. Strausz, R. Pottier, and G. P. Semeluk,Chem. Phys. Letters,13, 608 (1972); Y. Havada, J. B. Murrell, and H. H. Skeena,Chem. Phys. Letters,1, 595 (1968).

    Article  CAS  Google Scholar 

  12. J. A. Kerr and M. J. Parsonage, “Evaluated Kinetic Data on Gas Phase Addition Reactions,” Butterworths, London, 1972.

    Google Scholar 

  13. D. Mihelcic, V. Schubert, F. Hofler, and P. Potzinger,Ber. Bunsenges. Phys. Chem.,79, 1230 (1975).

    CAS  Google Scholar 

  14. L. C. Glasgow, G. Olbrich, and P. Potzinger,Chem. Phys. Letters,14, 466 (1972).

    Article  CAS  Google Scholar 

  15. A. G. Alexander, R. W. Fair, and O. P. Strausz,J. Phys. Chem.,78, 203 (1974).

    Article  CAS  Google Scholar 

  16. K. Obi, H. S. Sandhu, H. E. Gunning, and O. P. Strausz,J. Phys. Chem.,76, 3911 (1972).

    Article  CAS  Google Scholar 

  17. R. D. Penzhorn and B. de B. Darwent,J. Chem. Phys.,55, 1508 (1971).

    Article  CAS  Google Scholar 

  18. J. Hong, Ph.D. Thesis, University of Detroit, 1972.

  19. D. T. Osborne,Diss. Abstr. B,31, 5908 (1971).

    Google Scholar 

  20. P. Potzinger, L. C. Glasgow, and B. Reimann,Z. Naturforsch,29a, 493 (1974).

    Google Scholar 

  21. D. Mihelcic, P. Potzinger, and R. N. Schindler,Ber. Bunsenges. Phys. Chem.,78, 82 (1974).

    CAS  Google Scholar 

  22. D. Mihelcic, V. Schubert, R. N. Schindler, and A. Potzinger,J. Phys. Chem.,81, 1543 (1977).

    Article  CAS  Google Scholar 

  23. B. Reimann and P. Potzinger,Ber. Bunsenges. Phys. Chem.,80, 565 (1976).

    CAS  Google Scholar 

  24. E. R. Austin and F. W. Lampe,J. Phys. Chem.,81, 1134 (1977).

    Article  CAS  Google Scholar 

  25. G. K. Moortgat,Diss. Abstr. B,31, 1879 (1970).

    Google Scholar 

  26. J. A. Cowfer, K. P. Lynch, and J. V. Michael,J. Phys. Chem.,79, 1139 (1975).

    Article  CAS  Google Scholar 

  27. T. L. Pollock, H. S. Sandhu, A. Jodhan, and O. P. Strausz,J. Am. Chem. Soc.,95, 1017 (1973).

    Article  CAS  Google Scholar 

  28. E. R. Austin and F. W. Lampe,J. Phys. Chem.,80, 2811 (1976).

    Article  CAS  Google Scholar 

  29. B. Reimann, A. Mattern, R. Laupert, and P. Potzinger,Ber. Bunsenges. Phys. Chem.,81, 500 (1977)

    CAS  Google Scholar 

  30. K. Y. Choo, P. P. Gaspar, and A. P. Wolf,J. Phys. Chem.,79, 1752 (1975).

    Article  CAS  Google Scholar 

  31. D. Mihelcic, R. N. Schindler, and P. Potzinger,Ber. Bunsenges, Phys. Chem.,15, 1137 (1971).

    Google Scholar 

  32. M. A. Contineanu, D. Mihelcic, R. N. Schindler, and P. Potzinger,Ber. Bunsenges. Phys. Chem.,75, 426 (1971).

    CAS  Google Scholar 

  33. R. Walsh and J. M. Wells,J. Chem. Soc. Faraday I 72, 100 (1976).

    Article  CAS  Google Scholar 

  34. A. M. Doncaster and R. Walsh,J. Chem. Soc. Faraday I,72, 2908 (1976).

    Article  CAS  Google Scholar 

  35. A. Hosaka and F. S. Rowland,J. Phys. Chem.,77, 705 (1973).

    Article  CAS  Google Scholar 

  36. D(SiH3−H) was obtained by averaging three values: 94.0 kcal mol−1, W. C. Steele, L. D. Nichols, and F. G. A. Stone,J. Am. Chem. Soc.,84, 4441 (1962); 95.2 kcal mol−1, F. E. Saalfeld and H. J. Svec,J. Phys. Chem.,70, 1753 (1966); and 98.6 kcal mol−1, calculated by I.M.T. Davidson (ref. 6) from the data of P. Potzinger and F. W. Lampe,J. Phys. Chem.,73, 3912 (1969). The low value, 89±4 kcal mol−1, of P. Potzinger, A. Ritter, and J. Krause,Z. Naturforsch,30a, 347 (1975), was not considered in our evaluation. D(Si2H5−H) was evaluated by subtracting from D(SiH3−H) the average of the differences beween the two dissocation energies reported by M. Bowrey and J. H. Purnell,Proc. Roy. Soc. A,321, 341 (1971), and P. John and J. H. Purnell,J. Chem. Soc. Faraday I,69, 1455 (1973).

    Article  CAS  Google Scholar 

  37. K. Obi, A. Clement, H. E. Gunning, and O. P. Strausz,J. Am. Chem. Soc.,91, 1622 (1969).

    Article  CAS  Google Scholar 

  38. B. L. Mahoney,Diss. Abstr. B,27, 4347 (1967).

    Google Scholar 

  39. A. M. Doncaster and R. Walsh,J. Chem. Soc. Faraday I, 1978, in press.

  40. R. Wolfgang,Progr. React. Kinet.,3, 97 (1965).

    CAS  Google Scholar 

  41. J. Dubrin, C. MacKay, and R. Wolfgang,J. Chem. Phys.,44, 2208 (1966).

    Article  CAS  Google Scholar 

  42. P. P. Gaspar, P. Markusch, J. D. Holten III, and J. J. Frost,J. Phys. Chem.,76, 1352 (1972).

    Article  CAS  Google Scholar 

  43. O. F. Zeck, G. P. Gennaro, and Y.-N. Tang,J. Am. Chem. Soc.,67, 4498 (1975).

    Article  Google Scholar 

  44. T. Ogawa, G. A. Carlson, and G. C. Pimentel,J. Phys. Chem.,74, 2090 (1970).

    Article  CAS  Google Scholar 

  45. N. Basco and F. G. M. Hathorn,Chem. Phys. Lett.,8, 291 (1971).

    Article  CAS  Google Scholar 

  46. F. K. Truby and J. K. Rice,Int. J. Chem. Kinet.,5, 721 (1973).

    Article  CAS  Google Scholar 

  47. A. M. Bass and A. H. Laufer,Int. J. Chem. Kinet.,5, 1053 (1973).

    Article  CAS  Google Scholar 

  48. R. Hiatt and S. W. Benson,Int. J. Chem. Kinet.,4, 151 (1972).

    Article  CAS  Google Scholar 

  49. R. Hiatt and S. W. Benson,J. Am. Chem. Soc.,94, 6886 (1972).

    Article  CAS  Google Scholar 

  50. R. Hiatt and S. W. Benson,Int. J. Chem. Kinet.,4, 479 (1972).

    Article  CAS  Google Scholar 

  51. D. G. Hughes, R. M. Marshall, and J. H. Purnell,J. Chem. Soc. Faraday I,70, 594 (1974).

    Article  CAS  Google Scholar 

  52. A. Shepp,J. Chem. Phys.,24, 939 (1956).

    Article  CAS  Google Scholar 

  53. P. B. Ayscough,J. Chem. Phys.,24, 944 (1956).

    Article  CAS  Google Scholar 

  54. E. R. Morris and J. C. J. Thynne,J. Phys. Chem.,73, 3294 (1969).

    Article  CAS  Google Scholar 

  55. O. P. Strausz, E. Jakubowski, H. S. Sandhu, and H. E. Gunning,J. Chem. Phys.,51, 552 (1969).

    Article  CAS  Google Scholar 

  56. R. E. Berkley, I. Safarik, O. P. Strausz, and H. E. Gunning,J. Phys. Chem.,77, 1741 (1973).

    Article  CAS  Google Scholar 

  57. H. E. O’Neal, S. Pavlou, T. Lubin, M. A. Ring, and L. Batt,J. Phys. Chem.,75, 3945 (1971).

    Article  Google Scholar 

  58. E. Jakubowski, H. S. Sandhu, H. E. Gunning, and O. P. Strausz,J. Chem. Phys.,52, 4242 (1970).

    Article  CAS  Google Scholar 

  59. E. R. Morris and J. C. J. Thynne,Trans. Faraday Soc.,66, 183 (1970).

    Article  CAS  Google Scholar 

  60. R. E. Berkley, I. Safarik, H. E. Gunning, and O. P. Strausz,J. Phys. Chem.,77, 1734 (1973).

    Article  CAS  Google Scholar 

  61. J. A. Kerr, D. H. Slater, and J. C. Young,J. Chem. Soc. A 134 (1967).

  62. J. A. Kerr, D. H. Slater, and J. C. Young,J. Chem. Soc. A, 104 (1966).

  63. J. A. Kerr, A. Stephens, and J. C. Young,Int. J. Chem. Kinet.,1, 371 (1969).

    Article  CAS  Google Scholar 

  64. T. N. Bell and B. B. Johnson,Aust. J. Chem.,20, 1545 (1967).

    Article  CAS  Google Scholar 

  65. N. L. Arthur, J. R. Christie, and G. D. Mitchell, unpubished work.

  66. J. A. Kerr and D. M. Timlin,Int. J. Chem. Kinet.,3, 1 (1971).

    Article  CAS  Google Scholar 

  67. B. N. Ormson, W. D. Perrymore, and M. L. White,Int. J. Chem. Kinet.,9, 663 (1977).

    Article  CAS  Google Scholar 

  68. B. de B. Darwent, “Bond Dissociation Energies in Simple Molecules,”NSRDS-NBS 31 (1970)

  69. J. C. Amphlett and E. Whittle,Trans. Faraday Soc.,64, 2130 (1968).

    Article  CAS  Google Scholar 

  70. N. L. Arthur and B. R. Harman,Aust. J. Chem.,26, 1269 (1973).

    CAS  Google Scholar 

  71. J. A. Kerr, A. Stephens, and J. C. Young,Int. J. Chem. Kinet.,1, 339 (1967).

    Article  Google Scholar 

  72. A. U. Chaudhry and B. G. Gowenlock,J. Organometal. Chem.,16, 221 (1969).

    Article  CAS  Google Scholar 

  73. T. N. Bell and A. E. Platt,J. Phys. Chem.,75, 603 (1971).

    Article  CAS  Google Scholar 

  74. T. N. Bell and U. F. Zucker,J. Phys. Chem.,74, 979 (1970).

    Article  CAS  Google Scholar 

  75. J. A. Kerr and D. M. Timlin,Int. J. Chem. Kinet.,3, 69 (1971).

    Article  CAS  Google Scholar 

  76. T. N. Bell, Y. Yokota, and A. G. Sherwood,Can. J. Chem.,54, 2359 (1976).

    Article  CAS  Google Scholar 

  77. T. N. Bell and U. F. Zucker,Can. J. Chem.,48, 1209 (1970).

    Article  CAS  Google Scholar 

  78. W. J. Cheng and M. Szwarc,J. Phys. Chem.,72, 494 (1968).

    Article  CAS  Google Scholar 

  79. T. Shimanouchi, “Tables of Molecular Vibrational Frequencies, Part 2,”NSRDSNBS 11 (1967).

  80. J. L. Duncan,Spectrochim Acta.,20, 1807 (1964).

    Article  CAS  Google Scholar 

  81. S. Kaye and S. Tannenbaum,J. Org. Chem.,18, 1751 (1953).

    Google Scholar 

  82. J. E. Bassett and E. Whittle,J. Chem. Soc. Faraday I,68, 492 (1972).

    Article  CAS  Google Scholar 

  83. B. G. Tucker and E. Whittle,Trans. Faraday Soc. 61, 867 (1965).

    Google Scholar 

  84. N. L. Arthur and T. N. Bell,Can. J. Chem.,44, 1445 (1966).

    Article  CAS  Google Scholar 

  85. N. L. Arthur and P. Gray,Trans. Faraday Soc.,65, 434 (1969).

    Article  CAS  Google Scholar 

  86. S. H. Jones and E. Whittle,Int. J. Chem. Kinet.,2, 479 (1970).

    Article  CAS  Google Scholar 

  87. N. L. Arthur, K. F. Donchi, and J. A. McDonell,J. Chem. Soc. Faraday I,71, 2431 (1975).

    Article  CAS  Google Scholar 

  88. N. L. Arthur and K. F. Donchi, unpublished work.

  89. N. L. Arthur and J. A. McDonell,J. Chem. Phys.,57, 3228 (1972).

    Article  CAS  Google Scholar 

  90. P. Gray, A. A. Herod, A. Jones, and J. C. J. Thynne,Trans. Faraday Soc.,62, 2774 (1966).

    Article  CAS  Google Scholar 

  91. J. A. Kerr,Chem. Rev.,66, 465 (1966).

    Article  CAS  Google Scholar 

  92. G. O. Pritchard, H. O. Pritchard, and A. F. Trotman-Dickenson,Chem. and Ind., 564 (1955).

  93. C. L. Kibby and R. E. Weston, Jr.,J. Chem. Phys.,49, 4825 (1968).

    Article  CAS  Google Scholar 

  94. R. D. Giles, L. M. Quick, and E. Whittle,Trans. Faraday Soc.,63, 662 (1967).

    Article  Google Scholar 

  95. P. Gray and J. C. J. Thynne,Trans. Faraday Soc.,60, 1047 (1964).

    Article  CAS  Google Scholar 

  96. N. L. Arthur, P. Gray, and A. C. Lloyd,Trans. Faraday Soc.,65, 775 (1969).

    Article  Google Scholar 

  97. N. Imai, T. Dohmaru, and O. Toyama,Bull. Chem. Soc. Japan,38, 639 (1965).

    Article  CAS  Google Scholar 

  98. N. L. Arthur and P. Gray,Trans. Faraday Soc.,65, 434 (1969).

    Article  CAS  Google Scholar 

  99. J. A. Kerr and D. M. Timlin,J. Chem. Soc. A, 1241 (1969).

  100. T. N. Bell and A. E. Platt,Int. J. Chem. Kinet.,2, 299 (1970).

    Article  CAS  Google Scholar 

  101. T. N. Bell, P. Slade, and A. G. Sherwood,Can. J. Chem.,52, 1662 (1974).

    Article  CAS  Google Scholar 

  102. T. N Bell and P. J. Young,Can. J. Chem.,54, 1617 (1976).

    Article  CAS  Google Scholar 

  103. D. A. Edwards, J. A. Kerr, A. C. Lloyd, and A. F. Trotman-Dickenson,J. Chem. Soc. A, 621 (1966).

  104. E. R. Morris and J. C. J. Thynne,Trans. Faraday Soc.,64, 3021 (1968).

    Article  CAS  Google Scholar 

  105. N. L. Arthur, P. Gray, and A. A. Herod,Can. J. Chem.,47, 1347 (1969).

    Article  CAS  Google Scholar 

  106. N. L. Arthur and Min-See Lee,Aust. J. Chem.,29, 1483 (1976).

    CAS  Google Scholar 

  107. N. L. Arthur and K. S. Yeo,Aust. J. Chem.,25, 803 (1972).

    CAS  Google Scholar 

  108. T. N. Bell and A. E. Platt,Int. J. Chem. Kinet.,3, 307 (1971).

    Article  CAS  Google Scholar 

  109. F. A. Cotton and G. Wilkinson, “Advanced Inorganic Chemistry,” 3rd ed., Interscience, New York, N.Y., 1972.

    Google Scholar 

  110. P. Borrell and A. E. Platt,Trans. Faraday Soc.,66, 2286 (1970).

    Article  CAS  Google Scholar 

  111. R. D. Nelson, Jr., D. R. Lide, Jr., and A. A. Maryott, “Selected Values of Electric Dipole Moments for Molecules in the Gas Phase,”NSRDS-NBS 10 (1967).

  112. T. N. Bell and U. F. Zucker,Can. J. Chem.,47, 1701 (1969).

    Article  CAS  Google Scholar 

  113. T. N. Bell, R. Berkley, A. E. Platt, and A. G. Sherwood,Can. J. Chem.,52, 3158 (1974).

    Article  CAS  Google Scholar 

  114. T. N. Bell and A. E. Platt,Chem. Comm., 325 (1970).

  115. T. N. Bell and I. M. T. Davidson, unpublished work.

  116. P. Potzinger, A. Ritter, and J. Krause,Z. Naturforsch.,30a, 347 (1975).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physical Chemistry, La Trobe University, 3083, Melbourne, Victoria, Australia

    N. L. Arthur

  2. Department of Chemistry, Simon Fraser University, V5A 1S6, Burnaby, B.C., Canada

    T. N. Bell

Authors
  1. N. L. Arthur
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. N. Bell
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arthur, N.L., Bell, T.N. An evaluation of the kinetic data for hydrogen abstraction from silanes in the gas phase. Res Chem Intermed 2, 37–74 (1978). https://doi.org/10.1007/BF03055540

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03055540

Keywords

Search

Navigation