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Amperometric determination of palladium

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Abstract

Palladium (II) can be determined within + 0.5% in presence of nickel by amperometric titration with resacetophenone oxime either by (i) adding an excess of the oxime and titrating the excess with copper (II) in sodium acetate-acetic acid buffer; or by (ii) a direct titration using chloroform to prevent the palladium complex coming in contact with the mercury pool. However, this method cannot be adopted for the simultaneous determination of Pd and Ni.

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Authors and Affiliations

  1. Department of Chemistry, S. V. University College, Tirupati

    Y. Krishna Reddy, S. Brahmaji Rao & N. Appala Raju

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  1. Y. Krishna Reddy
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  2. S. Brahmaji Rao
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  3. N. Appala Raju
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Krishna Reddy, Y., Brahmaji Rao, S. & Appala Raju, N. Amperometric determination of palladium. Proc. Indian Acad. Sci. 81, 32–37 (1975). https://doi.org/10.1007/BF03051132

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  • DOI: https://doi.org/10.1007/BF03051132

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