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Molecular force fields for some anions and molecules of MX6 type (X = Cl, Br)

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Abstract

Force constants for six ions and one molecule, belonging to Oh point group, have been evaluated by using three different models for potential field. Validity of the methods has been discussed. Coriolis coupling constants, mean amplitudes of vibration and potential energy distribution for each mode have also been calculated.

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Author notes

  1. S. N. Thakur

    Present address: Department of Chemistry, University of Reading, England

Authors and Affiliations

  1. Department of Spectroscopy, Banaras Hindu University, Varanasi-5, India

    S. N. Rai, S. N. Thakur & D. K. Rai

Authors
  1. S. N. Rai
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  2. S. N. Thakur
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  3. D. K. Rai
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Additional information

Communicated by Dr. N. A. Narasimham,f.a.sc

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Rai, S.N., Thakur, S.N. & Rai, D.K. Molecular force fields for some anions and molecules of MX6 type (X = Cl, Br). Proc. Indian Acad. Sci. 74, 243–254 (1971). https://doi.org/10.1007/BF03050413

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  • DOI: https://doi.org/10.1007/BF03050413

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