Summary
The ultra-violet bands of S2 reported first by Rosen and Desirant are studied under high resolution. The bands are excited in a microwave (2450 mc./s.) discharge through sulphur vapour containing34S in natural abundance and enriched to 44·4%. Rotational analysis of six bands at 2620, 2660, 2760, 2793, 2813 and 2847 Å shows that they involve a common1Δ u −1Δ g system. The observed vibrational and rotational constants are
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Rosen, B. and Desirant, M...Bull. Soc. Roy. Sc. Liege, 1935,6–7, 233.
Haranath, P. B. V...Zeit. Für. Phy., 1963,173, 428.
Tomkins, F. S. and Fred, M...J. Opt. Soc. Am., 1957,47, 1087.
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Communicated by Dr. R. K. Asundi,f.a.sc.
An erratum to this article is available at http://dx.doi.org/10.1007/BF03046409.
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Narasimham, N.A., Brody, J.K. On the fine structure of the ultraviolet bands of S2 . Proc. Indian Acad. Sci. 59, 345–354 (1964). https://doi.org/10.1007/BF03049204
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DOI: https://doi.org/10.1007/BF03049204