Summary
It was shown that a solution of ferric chloride (0·08 N) could be satisfactorily employed as a permanent standard in the colourimetric estimation of nitrate by the α-naphthol sulphonic acid method. The close resemblance of the colours of the ferric chloride and the corresponding standard nitrate solution was established by analysing them making use of the Keuffel and Esser colour analyser.
Similar content being viewed by others
References
Yoe,Photometric Chemical Analysis, 1928,1, 316, etc.
Sprengel,Pagg. Ann., 1863,121, 188; Grandval and Lajowx,Compt. Rend., 1865,101, 62; Gill,J. Amer. Chem. Soc., 1894,16, 122; Chamot and Pratt,Ibid. J. Amer. Chem. Soc., 1909,31, 922;Ibid. J. Amer. Chem. Soc., 1910,32, 630; Redfield,Ibid. J. Amer. Chem. Soc., 1911,33, 366, 381.
Murty and Gopala Rao,Z. Anorg. Allg. Chemie, 1937,231, 298.
Narasimha Murty,Proc. Ind. Acad. Sci., 1938,7, 108.
Keuffel,J. Opt. Soc. Amer., 1925,11, 403; also Clark,The determination of hydrogen ions, 1928, 141.
Author information
Authors and Affiliations
Additional information
(Communicated by Prof. T. R. Seshadri)
Rights and permissions
About this article
Cite this article
Murty, G.V.L.N. Ferric chloride as a permanent standard in the colourimetric estimation of nitrate. Proc. Indian Acad. Sci. (Math. Sci.) 13, 116–118 (1941). https://doi.org/10.1007/BF03048821
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03048821