Abstract
Excess volumes, VE, of binary liquid mixtures (1) Toluene-Bromo-benzene, (2) Toluene-Nitrobenzene, (3) Toluene-Cyclohexanone, (4) Cyclo-hexane-Nitrobenzene, (5) Cyclohexane-Cyclohexanone were measured at 30° C. The results were analysed in terms of Flory’s theory. It is found that the theory, in general, is applicable to the mixtures studied.
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References
Flory, P. J...J. Amer. Chem. Soc., 1965,87, 1833.
Abe, A. and Flory, P. J.Ibid., 1965,87, 1838.
Kzuo Amya..Bull. Chem. Soc., Japan, 1961,34, 1271.
Naidu, P. R. and Krishnan, V. R.Trans. Faraday Soc., 1965,61, 1347.
—..J. Phys. Soc., Japan, 1965,20, 1954.
Naidu, P. R...Ibid., 1967,23, 1892.
Timmermans, J. ..Physico-Chemical Constants of Pure Oganic Compounds, (Elsevier Pub. Co., 1950).
Weissberger, A., Proskauer, E. S. Riddick, J. A. and Toops, E. E.Techniques of Organic Chemistry, Vol. VII, Interscience, Inc., New York, 1955.
Nigam, R. K. and Singh P. P.Ind. J. Chem., 1969,7, 156.
Benson, G. C. and Singh, J.J. Phys. Chem, 1968,75, 1345.
Prigogine, I., Bellemans, A. and Englert-Chowles, A.J. Chem. Phys., 1956,24, 518.
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Communicated by Prof. M. Santappa
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Raman, G.K., Naidu, P.R. Thermodynamics of binary liquid mixtures. Proc. Indian Acad. Sci. 77, 263–268 (1973). https://doi.org/10.1007/BF03048082
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DOI: https://doi.org/10.1007/BF03048082