Abstract
Rare earth perchlorate-antipyrine (ap) complexes of the formula Ln (ClO4)3.6 ap have been prepared and characterised. Infrared and electronic spectra showed the co-ordination through carbonyl oxygen. Conductivity and molecular weight data indicated a co-ordination number of six for these complexes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Dorfurt, E. W. and Schliephake, O.Z. anorg. u. allgem. chem., 1928,170, 129.
—————, 1929,183, 301.
Marsh, J. K. ..J. Chem. Soc., 1951, p. 1337.
Van Uitert, L. G. and Soden, R. R.J. Chem. Phys., 1962,36, 1797.
Patterson, G. E. and Bridenbaugh, P. M.J. Opt. Soc. Am., 1963,53, 299.
Baker, J. M. and Williams, F. I. B.Proc. Phys. Soc. (Lond.), 1961,78, 1340.
Romenow, W. J. and Treating, R. G.Preliminary Study of the Structure of Terbium Hexa-antipyrine, presented at the American Crystallographic Association Meeting, 31st July to 4th August 1961, University of Colorado.
Weissberger, A. and Proskauer, E. S.‘Organic Solvents’, Technique of Organic Chemistry, Interscience Publishers, Inc., New York, 1955, 7.
Kurz, E., Kober, G. and Berl, M.Analyt. Chem., 1958,30, 1983.
Kolthoff, I. M...Pharm. Weekbald, 1923,60, 194.
Quagliano, J. V., Fujita, J., Franz, G., Phillips, D. J., Walmsley, J. and Tyree, S. Y.J. Amer. Chem. Soc., 1961,83, 3770.
Walmsley, J. A. and Tyree, S. Y.Inorg. Chem., 1963,2, 312.
Glasstone, S...Text-Book of Physical Chemistry, Macmillan and Co., Ltd., London, 1956.
Bellamy, L. J...Infra-red Spectra of Complex Molecules, Methuen, London, 1954.
Serbi, G. and Alberti, C...Spectrochim. Acta, 1963,19, 1261.
Ramamurthy, P. ..Ph.D. Thesis, Indian Institute of Science, Bangalore, 1964.
Brown, R. D., Hukins, A. A., Lefevre, R. J. W., Northcott, N. and Wilson, I. R.J. Chem. Soc., 1949, p. 2812.
Veibel, S., Eggersen, K. and Linholt, S. C.Acta Chem. Scand., 1954,8, 768.
Bull, W. E., Madan, S. K. and Willis, J. E.Inorg. Chem., 1963,2, 303.
Ross, S. D...Spectrochim. Acta, 1962,18, 225.
Krishnamurthy, V. N. and Soundararajan, S.Z. anorg. a. allgem. Chem. (In press).
Gopalakrishnan, J., Ravi, A. and Patel, C. C.Indian J. Chem. (In press).
Author information
Authors and Affiliations
Additional information
Communicated by Prof. M. R. A. Rao,f.a.sc.
Rights and permissions
About this article
Cite this article
Krishnamurthy, V.N., Soundararajan, S. Antipyrine complexes of rare earth perchlorates. Proc. Indian Acad. Sci. 65, 148–153 (1967). https://doi.org/10.1007/BF03047542
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03047542