Summary
Dipole moment measurements have been made for the following phenyl hydrazine derivatives of carbonic acid, namely diphenyl carbohydrazide, diphenyl carbazone and diphenyl thiocarbazone in dioxan solution. The values obtained are 3·77, 3·80 and 2·50 (all in Debye units) respectively. The structures of these compounds have been discussed with particular reference to resonance in these molecules.
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References
Bates, W. W. and Hobbs, M. E.J. Am. Chem. Soc., 1951,73, 2151.
Denbigh, K. G...Trans. Faraday Soc., 1946,36, 936.
Halverstadt, I. F. and Kumler, W. D.J. Am. Chem. Soc., 1942,64, 2988.
Hedestrand, G...Z. Physik. Chem., 1929,13 (2), 428.
Hudson, H. and Hobbs, M. E.Rev. Sci. Instr., 1942,13, 140.
Hunter G. C. E. and Partington, J. R.J. Chem. Soc., 1933, 87 and 1252.
Kumler, W. D. and Fohlen, G. M.J. Am. Chem. Soc., 1942,64, 1944.
Raman, R. and Sundaresa SoundararajanProc. Ind. Acad. Sci., 1958,47A, 357.
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Smith, R. P., Ree, T. Magee, J. L. and Eyring, H.J. Am. Chem. Soc., 1951,73, 2263.
Soundararajan, S...Trans. Faraday Soc., 1957,53, 159.
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Communicated by Prof. K. R. Krishnaswami,f.a.sc.
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Subba Rao, B.S., Soundararajan, S. The dipole moments and molecular structure of phenylhydrazine derivatives of carbonic acid. Proc. Indian Acad. Sci. 50, 149–155 (1959). https://doi.org/10.1007/BF03047043
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DOI: https://doi.org/10.1007/BF03047043