Summary
Measurements of the time of setting of several alkali soap gels in pinene under different conditions show that they behave like organic gels; the time of setting increases with increase in temperature, and decreases with creasing concentration. The plots of logt≈1/T are straight lines, suggesting that Arrhenius’s equation is applicable to these systems; the values of the Heat of Activation have been calculated for each system. Setting points have also been measured. Molecular weight determinations show that a solution of either soap in pinene is a true solution at its boiling point.
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References
PrasadPresidential Address (Chem. Sec.)—20th Ind. Sc. Cong., 1941, 2.
OlsenJ. Phys. Chem., 1932,36, 529.
Prasad and co-workersCurr. Sci., 1940,9, 119, 459.
FlemmingZeit. Physik., 1902,41, 427.
Fells and FirthTrans. Farad. Soc., 1927,23, 623.
Hurd and LetteronJ. Phys. Chem., 1932,36, 606.
Prasad and HattiangadiJ. Indian Chem. Soc., 1929,6, 653
— and ParmarCurr. Sci., 1935,4, 310.
— and HattiangadiProc. Ind. Acad. Sci., 1945,21, 1.
PleassProc. Roy. Soc., 1930,126 A, 406.
Prasad and DesaiJ. Indian Chem. Soc., 1939,16, 117.
PickettJ. Ind. Eng. Chem. (Anal. Edn.), 1929,1, 36.
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Prasad, M., Hattiangdi, G.S. & Vishvanath, C.V. Studies in inorgano-organic gels in pinene. Proc. Indian Acad. Sci. 21, 56–65 (1945). https://doi.org/10.1007/BF03046944
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DOI: https://doi.org/10.1007/BF03046944