Preparation and properties of peroxy titanium malonate

  • G. V. Jere
  • C. C. Patel
Article
  • 18 Downloads

Abstract

The method of preparation and physicochemical properties of peroxy titanium malonate, TiO2(OOC)2CH2·3H2O are given. The reasons for the poor complexing tendency of malonic acid are discussed. The nature of the bonds between titanium and the peroxy as well as malonate groups is assigned from spectrophotometric and infra-red absorption studies.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Kharkar, D. P. and Patel, C. C.Proc. Ind. Acad. Sci., 1956,44 A, 287.Google Scholar
  2. 2.
    Jere, G. V. and Patel, C. C.Proc. Symposium on the Chem. of Co-ordination Compounds, Part II, 1960, p. 117 (Nat. Aead. Sci, India).Google Scholar
  3. 3.
    Sidgwick, N. V...The Chemical Elements and their Compounds, Vol. II, The Clarendon Press, Oxford, 1950, p. 871.Google Scholar
  4. 4.
    Patel, C. C. and Jere, G. V.Proc. 7th International Conference on Co-ordination Chem., Stockholm, 1962, p. 304.Google Scholar
  5. 5.
    Prasad, N. S. K. and Patel, C. C.Jour. Ind. Inst. Sci., 1954,36, 23.Google Scholar
  6. 6.
    Schmelz, M. J., Nakagawa, I., Mizushima, S. and Quagliano, J. V.J. Am. Chem. Soc., 1959,81, 287.CrossRefGoogle Scholar
  7. 7.
    Jere, G. V. and Patel, C. C.Nature, 1962,194, 470.CrossRefGoogle Scholar
  8. 8.
    ----- ..Z. anorg. allegem. Chem. (In press).Google Scholar
  9. 9.
    Harvey, A. E. and Manning, D. L.J. Am. Chem. Soc., 1950,72, 4488.CrossRefGoogle Scholar
  10. 10.
    Jeffrey, G. A. and Parry, G. S.Nature, 1952,169, 1105.CrossRefMathSciNetGoogle Scholar
  11. 11.
    Shahat, M...Acta Cryst., 1952,5, 763.CrossRefGoogle Scholar
  12. 12.
    Goedkoop, J. A. and MacGillavry, C. H. Ibid., 1957,10, 125.CrossRefGoogle Scholar
  13. 13.
    Clark, L. W...J. Phys. Chem., 1961,65, 2271.CrossRefGoogle Scholar
  14. 14.
    Jere, G. V. and Patel, C. C.J. Inorg. Nuclear Chem., 1961,20, 343.CrossRefGoogle Scholar
  15. 15.
    Cotton, F. A...Modern Co-ordination Chemistry, edited by Lewis, J. and Wilkins, R. G. (Interscience Publishing Co., Inc., New York), 1960, p. 301.Google Scholar
  16. 16.
    Pitzer, K. S. and Hildebrand, J. H.J. Am. Chem. Soc., 1941,63, 2472.CrossRefGoogle Scholar
  17. 17.
    Mason, S. F...Quart. Revs., 1961,15, 287.CrossRefGoogle Scholar

Copyright information

© Indian Academy of Sciences 1963

Authors and Affiliations

  • G. V. Jere
    • 1
  • C. C. Patel
    • 1
  1. 1.Department of Inorganic and Physical ChemistryIndian Institute of ScienceBangalore

Personalised recommendations