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Investigations in non-aqueous solvents

Part III.1 solubility and conductances of some metal nitrites in ethylenediamine and monoethanolamine

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Summary

  1. 1.

    Solubilities of nitrites of sodium, potassium and silver have been determined in anhydrous ethylenediamine and monoethanolamine.

  2. 2.

    Silver nitrite forms a crystalline solvate with ethylenediamine with this formula AgNO2-2 [C2H4(NH2)2].

  3. 3.

    The ethylenediamine solutions of silver and sodium nitrites are more conducting than those of monoethanolamine; however, potassium nitrite behaves contrary to the above trend.

  4. 4.

    Sodium nitrite shows a conductance minimum in ethylenediamine but not in monoethanolamine. Such behaviour has been encountered in ethylenediamine with mercuric cyanide13.

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References

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Authors and Affiliations

  1. Chemistry Department, Presidency College, Madras

    T. Muniyappan & B. Anjaneyalu

Authors
  1. T. Muniyappan
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  2. B. Anjaneyalu
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Additional information

Communicated by Dr. T. R. Govindachari,f.a.sc.

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Muniyappan, T., Anjaneyalu, B. Investigations in non-aqueous solvents. Proc. Indian Acad. Sci. 46, 454–461 (1957). https://doi.org/10.1007/BF03045958

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  • DOI: https://doi.org/10.1007/BF03045958

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