Summary
Chrysin forms a yellow coloured complex with thorium. This colour reaction has been investigated and utilised for spectrophotometric determination of thorium. The colour has maximum intensity at pH 2·8. It obeys Beer-Lambert’s law at 380 mµ between the concentration limits of 2 and 36 p.p.m. of thorium. The molar composition of the complex has been found to be 1:1.
Similar content being viewed by others
References
Mary, H. Fletcher and Robert, G. M.Science, 1954,119, 445–46.
Purshottam, A...Z. anal. Chem., 1955,145, 245–48.
Moeller, T. and Tecotzky, M.Anal. Chem., 1955,27, 1056–58.
Rao, B. R. L. and Patel, C. C.Proc. Ind. Acad. Sci., 1955,42 A, 317–25.
Kanno, T...Japan Analyst, 1960,9, 316.
Braham Dev and Jain, B. D.J. Less Common Metals, 1962,4, 286–90.
Rao, K. V., Rao K. V. and Seshadri, T. R.Proc. Ind. Acad. Sci., 1947,25 A, 428.
Job, P...Ann. Chim., 1928,9, 113.
Vosburgh, W. C. and Cooper, G. R.J. Amer. Chem. Soc., 1941,63, 437.
Harvey, A. E. and Manning, D. L. Ibid., 1950,72, 4488.
Author information
Authors and Affiliations
Additional information
Communicated by Prof. T. R. Seshadri,f.a.sc., f.r.s.
Rights and permissions
About this article
Cite this article
Katyal, M., Singh, R.P. Spectrophotometric determination of thorium using chrysin. Proc. Indian Acad. Sci. 56, 125–129 (1962). https://doi.org/10.1007/BF03045862
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03045862