Summary
Dipole moment measurements have been made in the case of a few aromatic hydrocarbon picrates, the values obtained being 2·18, 2·25, 2·97 (all in Debye units) for picrates of naphthalene, acenaphthene and phenanthrene respectively and the results discussed in terms of Mulliken’s theory. Measurements have also been extended to include a few salt-like heterocyclic amine picrates.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Abrahams, S. C...J. Amer. Chem. Soc., 1952,74, 2692.
Anderson, H. D. and Hammick, D. Ll.J. Chem. Soc., 1950, 1089.
Andrews, L. J...Chem. Revs., 1954,54, 713.
Bell, R. P. and Fendley, J. A.Trans. Faraday Soc., 1949,45, 121.
Brackman, W...Rec. trav. chim., 1949,68, 147.
Briegleb, G. and Czekalla, J.Z. Elektrochem., 1954,58, 249; 1955,59, 184.
Gardner, P. D. and Stump, W. E.J. Amer. Chem. Soc., 1957,79, 2759.
Harding, T. T. and Wallwork, S. C.Acta Cryst., 1955,8, 787.
Hulett, J. R., Pegg, J. A. and Sutton, L. E.J. Chem. Soc., 1955, 3901.
Jerslev, B...Acta Cryst., 1948,1, 21.
Kainer, H. and Otting, W.Ber., 1955,88, 1921.
—— and Uberle, A...Ibid., 1955,88, 1147.
Ketelaar, J. A. A...Chem. Weekblad, 1956,52, 218.
Kortum, G. and Walz, H.Z. Elektrochem., 1953,57, 73.
Kronberger, H. and Weiss, J.J. Chem. Soc., 1944, 464.
Kuboyama, A. and Nagakura, S.J. Amer. Chem. Soc., 1955,77, 2644.
Maryott, A. A...J. Res. Natl. Bureau of Standards (U.S.), 1948,41, 1 and 7.
Midovich, E. Ya and Gorbachev, S. V.Zhur. Fiz. Khim. 1953,27, 1404 and 1686;C.A., 1955,49, 95932; 1954,48, 4908.
Mulliken, R. S...J. Amer. Chem. Soc., 1952,74, 811.
—————..J. Phys. Chem., 1952,56, 801.
——, Rieke, C. A. and Orloff, H.J. Chem. Phys., 1949,17, 1248.
Orgel, L. E...Quart. Revs., 1954,8, 422.
——, Cottrell, T., Dick, W. and Sutton, L. E.Trans. Faraday Soc., 1951,47, 113.
Pfeiffer, P...Organische Molekul Verbindungen, 2nd Edition, Ferdinan Enke, Stuttgart, Germany, 1927.
Powell, H. M., House, G. and Cooke, P. W.J. Chem. Soc., 1943, 153.
Ross, S. D. and Kuntz, I.J. Amer. Chem. Soc., 1954,76, 74.
Shinomiya, C...Bull. Chem. Soc., Japan, 1945,15, 259.
Sobczyk, L. and Syrkin, Ya, K.Rocznicki. Chem., 1957,31, 197;C.A. 1957,51, 14347.
Soundararajan, S...Trans. Faraday Soc., 1957,53, 159.
Tsubomura, H...Bull. Chem. Soc., Japan, 1958,31, 435.
Weiss, J. ..J. Chem. Soc., 1942, 245.
Witschonke, C. R. and Kraus, C. A.J. Amer. Chem. Soc., 1947,69, 2472.
Symposia on Complexes—Section IV.Rev. trav. chim., 1956,75, 845–84.
Author information
Authors and Affiliations
Additional information
Communicated by Prof. M. R. A. Rao,f.a.sc.
Rights and permissions
About this article
Cite this article
Raman, R., Soundararajan, S. Dipole moments and molecular structure of picrates of aromatic hydrocarbons and heterocyclic amines. Proc. Indian Acad. Sci. 54, 41–50 (1961). https://doi.org/10.1007/BF03045829
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03045829