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Solvent effect on C≡N vibration in Raman effect

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4. Summary

The effect of various solvents on the intensity of C≡N vibration of benzo and acetonitriles has been studied. It has been observed that the aliphatic and aromatic non-polar solvents have no effect on the aromatic and aliphatic nitriles respectively. In all other cases, a marked variation in intensity has been noticed. The intensity of C≡N vibration in Raman effect shows a diminution when the solvent is changed from carbon tetrachloride to chloroform while it shows a considerable increase in infra-red.

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Authors and Affiliations

  1. Department of Physics, Annamalai University, Annamalainagar

    K. Venkateswarlu F.A.Sc. & C. Balasubramanian

Authors
  1. K. Venkateswarlu F.A.Sc.
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  2. C. Balasubramanian
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Venkateswarlu, K., Balasubramanian, C. Solvent effect on C≡N vibration in Raman effect. Proc. Indian Acad. Sci. 53, 202–205 (1961). https://doi.org/10.1007/BF03045822

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  • DOI: https://doi.org/10.1007/BF03045822

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