Abstract
Liquid cadmium severely embrittles commercially pure titanium (titanium-55A), by reducing the elongation at fracture by about a factor of ten. A ductile-brittle transition is observed as the temperature is increased, with the transition temperature increasing as the strain rate is increased. At high temperatures and low strain rates the titanium is ductile; while it is brittle at low temperatures and high strain rates. Fracture in the embrittled condition occurs intergranularly. The dependence of the ductile-brittle transition temperature on strain rate correlates reasonably well with the dependence of flow stress on temperature and strain rate, using published theories of the ductile-brittle transition.
Similar content being viewed by others
References
W. Rostoker, J. M. McCaughey, and H. Markus:Embrittlement by Liquid Metals, Reinhold Publ. Corp., New York, 1960.
A. R. C. Westwood:Environment—Sensitive Mechanical Behavior, A. R. C. Westwood and N. S. Stoloff, eds., pp. 1–65, Gordon & Breach, New York, 1966.
Examination of Cracks in Titanium-Alloy Compressor Disc caused by Molten Cadmium, Westinghouse electric Corp., Aviation Gas Turbine Division, Titanium Metallurgical Laboratory, Battelle Memorial Institute, Columbus, Ohio, Memorandum Report, February 8, 1956.
Examination of Cracks in Titanium-Alloy Compressor Disc, Westinghouse Electric Corp., Aviation Gas Turbine Division, Titanium Metallurgical Laboratory, Battelle Memorial Institute, Columbus, Ohio, Memorandum Report, March 20, 1956.
D. W. Stough, F. W. Fink, and R. S. Peoples: The Stress Corrosion and Pyrophoric Behavior of Titanium and Titanium Alloys, TML Rept. No. 84, Sept. 15, 1957.
H. A. Johnson: Stress Cracking of Titanium, Tech. Mem. WCRT TM-56-97 Wright Air Dev. Center, Wright-Patterson AFB, Ohio, 20 Aug. 1956.
Ref. 1,Environment—Sensitive Mechanical Behavior, A. R. C. Westwood and N. s. Stoloff, eds., pp. 1–65, Gordon & Breach, New York, 1966. pp. 29–30.
M. Harrigan: X-15 Liquid Cadmium Embrittlement, Report No. TFD-68-276, North American Rockwell Corporation, Los Angeles Division, 8 March 1968.
A. H. Cottrell:Trans. TMS-AIME, 1958, vol. 212, pp. 192–203.
N. J. Petch:Fracture, B. L. Averbach, D. K. Felbeck, G. T. Hahn and D. A. Thomas, es., pp. 54–64, MIT Technology Press, New York, 1959.
H. Ichinose and C. Oouchi:Trans. Japan Inst. Met., 1968, vol. 9, pp. 41–47.
H. Ichinose:Trans. Japan Inst. Met., 1968, vol. 9, pp. 35–41.
H. Ichinose and C. Oouchi:Trans. Japan Inst. Met., 1968, vol. 9 Suppl., pp. 980–83.
A. N. Stroh:Adv. Phys., 1957, vol. 6, pp. 418–65.
A. R. C. Westwood, C. M. Preece, and M. H. Kamdar:Trans. Quart. ASM, 1967, vol. 60, pp. 723–25; A. R. C. Westwood and M. H. Kamdar:Phil. Mag., 1963, vol. 8, pp. 787–804; N. S. Stoloff and T. L. Johnston:Acta Met., 1963, vol. 11, pp. 251–56.
C. M. Preece and A. R. C. Westwood:Trans. Quart. ASM, 1969, vol. 62, pp. 418–25.
W. M. Robertson:Trans. TMS-AIME, 1966, vol. 236, pp. 1478–82.
E. N. Pugh: Ref. 2, pp. 351–401.
R. V. Schablaske, B. S. Tani, and M. G. Chasanov:Trans. TMS-AIME, 1962, vol. 224, pp. 867–68.
M. G. Chasanov, P. D. Hunt, I. Johnson, and H. M. Feder:Trans. TMS-AIME, 1962, vol. 224, pp. 935–39.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Robertson, W.M. Embrittlement of titanium by liquid cadmium. Metall Trans 1, 2607–2613 (1970). https://doi.org/10.1007/BF03038392
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF03038392