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Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative dehydrogenation ofn-butene to 1,3-butadiene

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Abstract

Multicomponent bismuth molybdates were prepared by a co-precipitation method for use in the oxidative dehydrogenation ofn-butene to 1,3-butadiene. The effect of divalent and trivalent metals on the catalytic performance of multicomponent bismuth molybdate catalysts was investigated. It was found that the metal ratio of Fe/Bi/Mo=3∶1∶12 was favorable for the reaction. The successful formation of Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts was well confirmed by XRD and ICP-AES measurements. The multicomponent bismuth molybdate catalysts showed a better catalytic performance than the pure γ-Bi2MoO6 catalyst. Among the Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts, Ni3Co5Fe3Bi1Mo12O50 showed the highest yield of 1,3-butadiene.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, 151-744, Seoul, South Korea

    Ji Chul Jung, Howon Lee, Heesoo Kim & In Kyu Song

  2. SK Corporation, Yuseong-ku, 305-712, Daejeon, South Korea

    Young-Min Chung, Tae Jin Kim, Seong Jun Lee, Seung-Hoon Oh & Yong Seung Kim

Authors
  1. Ji Chul Jung
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  2. Howon Lee
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  3. Heesoo Kim
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  4. Young-Min Chung
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  5. Tae Jin Kim
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  6. Seong Jun Lee
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  7. Seung-Hoon Oh
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  8. Yong Seung Kim
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  9. In Kyu Song
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Correspondence to In Kyu Song.

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Jung, J.C., Lee, H., Kim, H. et al. Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative dehydrogenation ofn-butene to 1,3-butadiene. Res. Chem. Intermed. 34, 827–833 (2008). https://doi.org/10.1007/BF03036944

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  • DOI: https://doi.org/10.1007/BF03036944

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