Cited References
J.L. Gay-Lussac and L.J. Thenard,Rech. Phys.-Chim., 1, 176 (1811); cited in [1874Tro1]. (Equi Diagram; Experimental)
L. Troost, and P. Hauteville, “On the Compounds of Hydrogen with the Alkaline Metals,”Comp. Rend., 78, 807–811 (1874) in French. (Equi Diagram; Experimental)
L. Troost, and P. Hauteville, “On the Alloys of Hydrogen with Metals. I. Alloys of Hydrogen with the AlkalineMetals,”Ann. Chim.Phys., 5 (11), 273–288 (1874) in French. (Equi Diagram; Experimental)
H. Moissan, “Preparation and Properties of the Sodium Hydride,”Comp. Rend., 134, 71–75 (1902) in French. (Equi Diagram, Crys Structure; Experimental)
M. de Forchand, “Heat of Formation of the Sodium Hydride. Acidity of the Hydrogen Molecule,”Comp. Rend., 140, 990–992 (1905) in French. (Thermo; Experimental)
F.G. Key, “The Dissociation Pressures of Sodium and Potassium Hydrides,”J. Amer. Chem. Soc., 34, 779–788 (1912). (EquiDiagram; Experimental)
F. Ephraim and E. Michel, “On Metal Hydrides I. Alkali Hydrides,”Helv. Chim. Acta, 4, 762–781 (1921) in German. (Equi Diagram; Experimental)
D.C. Bardwell, “Hydrogen as a Halogen in Metallic Hydrides,”J. Amer. Chem. Soc., 44, 2499–2504 (1922) (Equi Diagram; Experimental)
G. Joos and G.F. Huttig, “The Electro-Affinity of Hydrogen,”Z. Phys., 40, 331–332 (1926) in German. (Crys Structure; Experimental)
J. Kasarnowsky, “The Electro-Affinity of Hydrogen,”Z. Phys., 38, 12–21 (1926) in German. (Crys Structure; Experimental)
J. Kasarnowsky and M. Proskurnin, “The Electro-Affinity of Hydrogen and the Density of Alkali Hydride,”Z. Phys., 43, 512–515 (1927) in German. (Crys Structure; Experimental)
G.F. Huttig and F. Brodkorb, “Studies on the Chemistry of Hydrogen. VI. On the Binding of Hydrogen with Sodium,”Z. Anorg. Chem., 161, 353–362 (1939) in German. (Crys Structure; Experimental)
M. Proskurnin and J. Kasarnowsky, “On Saline Hydride,”Z. Anorg. Chem., 170, 301–310 (1928) in German. (Crys Structure; Experimental)
H. Hagen and A. Sieverts, “Sodium Hydride. I. Preparation and Density,”Z. Anorg. Chem., 185, 239–253 (1929) in German. (Crys Structure; Experimental)
H. Hagen and A. Sieverts, “Sodium Hydride. II. Heat of Formation,”Z. Anorg. Chem., 185, 254–266 (1929) in German. (Thermo; Experimental)
E. Zintl and A. Harder, “On Alkali Hydride,”Z. Phys. Chem., B 14, 265–284 (1931) in German. (Crys Structure; Experimental)
E.F. Sollers and J.L. Crenshaw, “The Dissociation Pressures of Sodium Deuteride and Sodium Hydride,”J. Amer. Chem. Soc., 59, 2724–2726 (1937). (Equi Diagram; Experimental)
C.G. Shull, E.G. Wollan, G.A. Morton, and W.L. Davidson, “Neutron Diffraction Studies of NaH and NaD,”Phys. Rev., 73, 842–847 (1948). (Crys Structure; Experimental)
A. Herold, “Dissociation Pressure of the Alkaline Hydride,”Compt. Rend., 228, 686–688 (1949) in French. (Equi Diagram; Experimental)
E.V. Sayre and J. Beaver, “Isotope Effect in the Vibrational Frequency Spectra and Specific Heats of Sodium Hydride and Deuteride,”J. Chem. Phys., 18, 584–594 (1950). (Thermo; Experimental)
A. Herold, “Contribution to the Study of the Alkaline Hydride,”Ann. Chim., Ser., 12, (6), 537–575 (1951) (Equi Diagram; Thermo; Experimental)
M.D. Banus, J.J. McSharry, and E.A. Sullivan, “The Sodium-Sodium Hydride-Hydrogen System at 500–600°C,”J. Am. Chem. Soc., 77, 2007–2010 (1955). (Equi Diagram; Experimental)
C.E. Messer, L.G. Fasolino, and C.E. Thalmayer, “The Heats of Formation of Lithium, Sodium and Potassium Hydrides,”J. Am. Chem. Soc, 77, 4524–4526 (1955). (Thermo; Experimental)
R.E. Elson, H.C. Hornig, W.L. Jolly, J.W. Kury, W.J. Ramsey, and A. Zalkin, Univ. California Rad. Lab. Rep., UCRL 4519 Rev. (June 1956); as cited in [60Lib]. (Crys Structure; Experimental)
D.D. Williams, J.A. Grand, and R.R. Miller, “The Solubility of Sodium Hydride in Sodium,”J. Phys. Chem., 61, 379–381 (1957). (Equi Diagram; Experimental)
S.R. Gunn and L.G. Green, “The Heats of Formation at 25 °C of the Crystalline Hydrides and Deutendes and Aqueous Hydroxides of Lithium, Sodium and Potassium,”J. Am. Chem. Soc., 80, 4782–4785 (1958). (Thermo; Experimental)
G.G. Libowitz, “The Nature and Properties of Transition Metal Hydrides,”J. Nucl. Mater., 2, 1–22 (1960). (Crys Structure; Review)
V.G. Kuznetsov and M.M. Shkrabkina, “X-Ray Diffraction Study of NaH and KH at Temperatures from 20 to 400 °C,”Zh. Strukt. Khim., 3, 553–558 (1962) in Russian; TR:J. Struct. Chem., 3, 532–537 (1962). (Crys Structure; Experimental)
G.A. Sullivan and J.W. Weymouth, “Measurement of the Equilibrium Net Vacancy Concentration in Sodium,”Phys Rev., 136, A1141-A1148 (1964). (Crys Structure, Experimental)
C.C. Addison, R.J. Pulham, and R.J. Roy, “Liquid Metals. Part X. Solutions of Hydrogen in Liquid Sodium,”J. Chem. Soc. (London), Parti, 116–121 (1965). (Equi Diagram; Experimental)
G.G. Libowitz,The Solid-State Chemistry of Binary Metal-Hydrides, W.A. Benjamin, Inc., New York, 50–90 (1965). (Thermo; Compilation)
D.W. McClure and G.D. Halsey, Jr., “The Solubility of Hydrogen in Liquid Sodium,”J. Phys. Chem., 69, 3542–3547 (1965). (Equi Diagram; Experimental)
S.R. Gunn, “The Heats of Formation at 25°C of the Crystalline Hydrides and Aqueous Hydroxides of Rubidium and Cesium,”J. Phys. Chem., 71, 1386–1390 (1967). (Thermo; Experimental)
C.B. Magee, “Saline Hydride,”Metal Hydrides, W.M. Mueller, J.P. Blackledge and G.G. Libowitz, Ed., Academic Press, New York, 165–240 (1968). (Thermo; Compilation)
R.J. Newcombe and J. Thompson, “An Electrochemical Method for the Determination of the Solubility of Hydrogen in Liquid Sodium,”J. Polarog. Soc., 14, 104–108 (1968). (Equi Diagram; Experimental)
S.A. Meacham, E.F. Hill, and A.A. Gordus, “The Solubility of Hydrogen in Sodium,” APDA-241, Atomic Power Development Associates (1970); as cited in [74Vis]. (Equi Diagram; Experimental)
P. Roy and D.N. Rodgers, “Characterization of a Diffusion Tube Hydrogen Detector in a Dynamic Sodium System,”Nucl. Technol., 12, 388–392 (1971) (Equi Diagram, Thermo; Experimental)
D.R. Vissers, J.T. Holmes, P.A. Nelson and L.G. Bartholme “A Hydrogen Monitor for Detection of Leaks in LMFBR Steam Generators,”Nucl. Technol, 12, 218 (1974). (Equi Diagram; Experimental)
J. Rohde and M. Hissink, private communication, Central Tech. Inst., Apeldoorn, Netherlands (1972); cited in [74Vis]. (Equi Diagram; Experimental)
V. Prochazka and M. Nedved, “On the Chemistry of Metal Hydrides, V. The Kinetics of the Formation of Sodium Hydride,”Coll. Czech. Chem. Commun., 38, 2845–2849 (1973). (Equi Diagram; Experimental)
V. Prochazka and M. Nedved, “On the Chemistry of Metal Hydrides,VI. The Mechanism of the Formation of Sodium Hydride Catalysed by Carbon Monoxide,”Coll. Czech. Chem. Commun., 38, 2850–2854 (1973). (Equi Diagram; Experimental)
R.J. Pulham and P.A. Simm, “Solutions of Hydrogen and Oxygen in Liquid Sodium,”Chemical Aspects of Corrosion and Mass Transfer in Liquid Sodium, S. Jansen, Ed., Metallurgical Society, AIME, New York, 317–322 (1973). (Equi Diagram; Experimental)
D.R. Vissers, J.T. Holmes, L.G. Bartholme, and P.A. Nelson, “A Hydrogen-Activity Meter for Liquid Sodium and its Application to Hydrogen Solubility Measurements,”Nucl. Technol., 21, 235–244 (1974). (Equi Diagram; Experimental)
L.C. Chhabildas and A.L. Ruoff, “Isothermal Equation of State for Sodium Chloride by the Length-Change-Measurement Technique,”J. Appl. Phys., 47, 4182–4187 (1976). (Pressure; Experimental)
O.A. Skuratov, O.N. Pavlov, V.I. Danikin and I.V. Volkov, “Dissociation Pressure of Molten Stoichiometric Alkali Metal Hydrides,”Zh. Neorg. Khim., 21, 2910–2913 (1976) in Russian; TR:Russ. J. Inorg. Chem., 21, 1605–1608 (1976). (Equi Diagram, Thermo; Experimental)
I.O. Bashkin, T. N. Dymova, and E.G. Ponyatovskii, “On the Structural Transition from NaCl to CsCl Type in Alkali Hydrides,”Phys. Stat. Solidi.(b), 100, 87–92 (1980). (High Pressure; Experimental)
J.R. Cwyther and A.C. Whittingham, “The Kinetics of Hydrogen Removal from Liquid Sodium,”Mater. Behav. Phys. Chem. Liq. Met. Syst., Proc. Conf., H.V. Borgstedt, Ed., Plenum, New York, 335–343 (1982). (Equi Diagram; Experimental)
W. Klostermeier and E.U. Franck, “Liquid Mixtures of Sodium and Sodium Hydride at High Pressures and Temperatures,”Ber. Bunsenges. Phys. Chem., 86, 606–612 (1982) in German. (Equi Diagram, Thermo; Experimental)
F. Perrot and M. Rasolt, “Lattice Relaxation and Tendency for Crystallographic Distortions Around a Hydrogen Impurity in the Alkali Series,”Phys. Rev. B, 25, 7327–7330 (1982). (Crys Structure; Theory)
R.S. Fidler and R. Saagi, “The Crystallization Behaviour of Sodium Oxide and Sodium Hydride from Liquid Sodium,”Nucl. Energy, 23, 385–398 (1984). (Equi Diagram; Experimental)
Yu.P. Krasnyi and E.Z. Kolesnichenko, “Interionic Interaction of Hydrogen Solutions in Liquid Sodium and Potassium,”Ukr. Fiz. Zh., 29, 1322–1327 (1984) in Russian. (Equi Diagram; Theory)
H.D. Hochheimer, K. Strossner, W. Honle, B. Baranowski and F. Filipek, “High Pressure X-Ray Investigation of the Alkali Hydrides NaH, KH, RbH and CsH,”J. Less-Common Met., 107, L13-L14 (1985). (Pressure; Experimental)
H.D. Hochheimer, K. Strossner, W. Honle, B. Baranowski, and F. Filipek, “High Pressure X-Ray Investigation of the Alkali Hydrides NaH, KH, RbH and CsH,”Z. Phys. Chem. New Folge, 143, 139–144 (1985). (Pressure; Experimental)
E.G. Ponyatovskii and I.O. Bashkin, “New Phase Transitions in Hydrides of the I-A, III-A, and IV-A Group Metals,”Z. Phys. Chem., New Folge, 146, 137–157 (1985). (High Pressure; Experimental)
G.M.S. Shivastava, G.G. Agrawal, and J. Shanker, “Thermodynamic Properties and the Equation of State of Alkali Hydride Crystals,”Pkys. Status Solidi. (b), 135, 529–534 (1986). (Pressure; Theory)
H.A. Wriedt, “The Na-O (Sodium-Oxygen) System,”Bull. Alloy Phase Diagrams, 8(3), 234–246 (1987). (Crys Structure; Review)
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This work was supported by a grant from ASM INTERNATIONAL. Literature searched through 1987. Professor Manchester is the ASM/NIST Data Program Co-Category Editor for binary hydrogen alloys.
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San-Martin, A., Manchester, F.D. The H-Na (Hydrogen-Sodium) system. Bulletin of Alloy Phase Diagrams 11, 287–294 (1990). https://doi.org/10.1007/BF03029300
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DOI: https://doi.org/10.1007/BF03029300