Abstract
Rare outcrops of a glassy rock very similar to an obsidian occur among the Permian volcanics of the Lugano region, about 15 km North of Varese (Italy). Such a rock is known as «vitrofiro di Gràntola» (the «vitrophyric dacite» of Stille and Buletti, 1987, 262 Ma in age). XRF analyses for major and some trace elements performed on four selected samples indicate a rhyodacitic chemistry with a calcalkaline affinity for these rocks. Microprobe analyses of Mg-Fe and Fe-Mg-orthopyroxene, Fe-augite, Fe-pargasite, Fe-edenite, Fe-olivine, plagioclase, sanidine and allanite are given as a support for the pre-eruption differentiation history.
Riassunto
Circa 15 km a Nord di Varese (Italia), si osservano limitati affioramenti di una roccia dall’aspetto vetroso, molto simile a quello di un’ossidiana, facente parte delle vulcaniti permiane del Luganese. Tale roccia, conosciuta come «vitrofiro di Gràntola», corrisponde allavitrophyric dacite datata 262 Ma da Stille e Buletti (1987). La composizione (determinata con XRF) in element! maggiori, minori ed in traccia di 4 campioni opportunamente selezionati, dimostra il loro carattere riodacitico con affinità calcalcalina. La composizione, determinata alla microsonda elettronica, dei minerali femici (orto-e clinopirosseni, anfiboli, olivine), sialici (plagioclasi e sanidino) e di un’allanite ha fornito un contribute) alla comprensione del processo evolutivo precedente alla messa in posto.
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Blbliografia
Amoretti A., 1794.Viaggio da Milano ai tre laghi. Milano.
Brooks C. K., Henderson P., Rønsbo J. G., 1981.Rare Earth partition between allamte and glass in the obsidian of Sandy Braes, Northern Ireland. Min. Mag., 44: 157–160.
Brown W. L., Parsons I., 1981.Towards a more practical two-feldspar geothermometer. Contrib. Mineral. Petrol., 76: 369–377.
Buletti M., 1985.Petrographisch-geochemische Untersuchungen im Luganer Porphyrgebiet. Diss. Univ. Bern: 1–157.
Carmichaei I. S. E., 1960.The pyroxenes and olivines from some Tertiary Acid Glasses. Journ. Petrol., 1: 309–336.
Carmichael I. S. E., 1967.The mineralogy and petrology of the volcanic rocks from the Leucite Hills, Wyoming. Contrib. Mineral. Petrol., 15: 24–66.
Coats R. R., 1968.The Circle Creek rhyolite, a volcanic complex in northern Elko County, Nevada. Mem. Geol. Soc. America, 116: 69–106.
Colby J. W., 1971.Magic IV, a computer program for quantitative electron microprobe analysis. Bell Telephone Laboratories, Allentown, Pennsylvania.
Gundari A., Salvtulo G., 1989.Ti solubility in diopsidic pyroxene from a suite of New South Wales leucitites (Australia). Lithos, 22: 191–198.
De Sitter L., 1939.Les porphyres luganois et leurs enveloppes. Leid. Geol. Med., 11: 19–77.
Duggan M. B., 1976.Primary allanite in vitrophyric rhyolites from the Tweed Sield volcano, north-eastern New South Wales. Min. Mag., 40: 652–653.
Exley R. A., 1980.Microprobe studies of REE-rich accessory minerals: implication for Skye granite petrogenesis and REE mobility in hydrothermal systems. Earth Planet. Sc. Lett., 48: 97–110.
Harada T., 1883.Das Luganer Eruptivgebiet. Neues Jahrb. F. Min. B., 2: 1–48.
Harloff Ch. E. A., 1927.The geology of the porphyry district of Lugano between Ponte Tresa and Luino. Leid. Geol. Med., 2: 115–222.
Helz R. T., 1973.Phase relationship of basalts in their melting range at Ph 2o = 5 Kb as a function of oxygen fugacity. J. Petrol, 14: 249–302.
Isshiki N., 1963.Petrology of Hachijo-jima volcanic group, Seven Izu Island, Japan. J. Fac. Sc. Univ. Tokyo, 15: 91–134.
Jakes P., White J. R., 1972.Major and trace element abundances in volcanic rocks of orogenic areas. Geol. Soc. of Amer. Bull., 83: 29–40.
Koomans C. M., 1937.Der Chemismus des Luganer Porphyrgebietes. Leid. Geol. Med., 9: 19–77.
Kuno H., 1969.Pigeonite-bearing andesite and associated dacite from Asio, Japan. Am. Journ. Sc., 267-A: 257–268.
Lindsley D. H., 1983.Pyroxene thermometry. Am. Min., 68: 477–493.
Mitropoulos P., 1987.Primary allanite in andesitic rocks from the Poros Volcano, Greece. Min. Mag., 51: 601–604.
Morimoto N., Faeries J., Ferguson A. K., Ginzburg I. V., Ross M., Seifert F. A., Zussman J., 1988.Nomenclature of pyroxenes. Am. Min., 73: 1123–1133.
Muir I. D., 1954.Crystallization of pyroxenes in an iron-rich diabase from Minnesota. Min. Mag., 30: 376–388.
Muñoz M., Sagredo J., 1974.Clinopyroxenes as geobarometnc indicators in mafic and ultramafic rocks from Canary Island. Contr. Mineral. Petrol., 44: 139–147.
Peccerillo A., Taylor S. R., 1976.Geochemistry of Eocene calc-alkaline volcanic rocks from the Kastamonu Area, northern Turkey. Contrib. Mineral. Petrol., 58: 63–81.
Rock N. M. S., Leake B. E., 1984.International Mineralogical Association amphibole nomenclature scheme: computerization and its consequences. Min. Mag., 48: 211–227.
Rode K. P., 1941.The geology of the Morcote Peninsula and the petrochemistry of the porphyry magma of Lugano. Schweiz. Mineral. Petrogr. Mitt., 21: 194–312.
Stille P., Bulettt M., 1987.Nd-Sr isotopic characteristics of the Lugano volcanic rocks and constraints on the continental crust formation in the South Alpine domain (N-Italy-Switzerland). Contrib. Mineral. Petrol., 96: 140–150.
Thompson R. N., 1974.Some high pressure pyroxenes. Min. Mag., 39: 768–787.
Wass S. Y., 1979.Multiple origin of clinopyroxenes in alkali basaltic rocks. Lithos, 12: 115–132.
Zanettin B., 1986.Classificazione chimica delle rocce vulcaniche mediante il diagramma T.A.S. (Total Alkali-Silica). Rend. Soc. It. Min. Petr., 41: 193–200.
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Nella seduta del 10 novembre 1990.
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Bocchio, R., Crespi, R., Capitani, L.D. et al. Caratteri chimici e mineralogici del «vitrofiro di Gràntola» (Varese). Rend. Fis. Acc. Lincei 2, 39–49 (1991). https://doi.org/10.1007/BF03010411
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DOI: https://doi.org/10.1007/BF03010411