Skip to main content
SpringerLink
Log in

Graft polymerization of acrylic acid and acrylamide onto BOPET corona films

  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The graft polymerization of acrylic acid (A) and acrylamide (B) was carried out onto bi-oriented polyester BOPET corona film. The influence of monomer concentration, reducer concentration and reaction time on the graft polymerization was investigated. The surface tension of the films increased with an increase of monomer concentration, till the concentration of monomer A reached 1.5 × 10-2 g/mL and the concentration of monomer B reached 4.0 × 10-2 g/mL. The surface tension of the films reached a maximum value at 7 × 10-4 M of reducer concentration and subsequently decreased with further increase in reducer concentration. The surface tension of the films increased with the increase of the reaction time apparently within 50min. The grafted corona BOPET films were characterized with IR and XPS. The presence of graft on the film surface was confirmed. The attenuation experiments on grafted corona BOPET films in air at 50°Cand in water were carried out to investigate the persistence of graft polymerization of acrylic acid and arylamide onto BOPET corona films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yin Yanping.Two-way Stretched Polyester Film. Beijing: Chemistry Industry Publishing House, 1998

    Google Scholar 

  2. Haidare H, Vallat M F. Hot Air Treatment of Poly (Ethylene Terephthalate) Film: Experimental and Theoretical Verifications of the Carboxylation Hypothesis.European Polymer Journal, 1993, 29(7): 899–902

    Article  Google Scholar 

  3. Le Quoc, Joan, Pireaux. Surface modification of PET Films with RF Plasma and Adhesion ofin situ Evaporated Al on PET.Surface and Interface Analysis, 1994, 22(1): 224–229

    Article  Google Scholar 

  4. Watanake, Hirosuke, Jakat. Polymer Surface Modification Due to Excimer Laser Radiation-chemical and Physical Changes in the Surface Structure of PET.Polymer International, 1993, 31(3): 247–254

    Article  Google Scholar 

  5. Luo Laichun, Yang Shikun. The Corona Treatment and Application of Polyester Film.Polyester Industry, 2000, 12(4): 20–22

    Google Scholar 

  6. Zhang Sheng-minet al. Surface Modification of Hydroxyapatie by Using γ-aminopropyl Silane.Journal of Wuhan university of Technology-Mater. Sci. Ed. 2001, 16(3): 37–38

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Environment and Chemistry Department, Wuhan Institute of Science and Technology, 430073, Wuhan, China

    Sun Jie (Lecture; Master)

  2. Harbin Institute of Technology, China

    Tian Hua-yu & Bai Yong-ping

Authors
  1. Sun Jie
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tian Hua-yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bai Yong-ping
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Funded by the National Natural Science Foundation of China (No.50309011)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sun, J., Tian, Hy. & Bai, Yp. Graft polymerization of acrylic acid and acrylamide onto BOPET corona films. Journal of Wuhan University of Technology-Mater. Sci. Ed. 19, 90–93 (2004). https://doi.org/10.1007/BF03000180

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03000180

Key words

Search

Navigation