Abstract
The order of toxicity of triphenyltin chloride > trans-2-hydroxycyclohexyl-triphenyltin > cyclohexyltriphenyltin was established, when these compounds were assayed againstTribolium confusum. Larval growth retardation, probably due to an antifeedant effect, was observed with all three compounds. The higher activity oftrans-2-hydroxycyclohexyltriphenyltin compared with that of cyclohexyltriphenyltin may be due to a metabolic deoxystannylation reaction, which produces a triphenyltin derivative and cyclohexene.
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Ascher, K.R.S. and Ishaaya, I. (1973) Antifeeding and protease- and amylase-inhibiting activity of fentin acetate inSpodoptera littoralis larvae.Pestic. Biochem. Physiol. 3: 326–336.
Ascher, K.R.S. and Nissim, S. (1964) Organotin compounds and their potential use in insect control.Wld Rev. Pest Control 3: 188–211.
Ascher, K.R.S. and Nissim, S. (1965) Quantitative aspects of antifeeding: comparing “anti-feedants” by assay withProdenia litura.Int. Pest Control 7(4): 21–24.
Ascher, K.R.S. and Rones, G. (1964) Fungicide has residual effect on larval feeding.Int. Pest Control 6(3): 6–9.
Bock, R. (1981) Triphenyltin compounds and their degradation products.Residue Rev. 79: 1–270.
Fish, R.H. and Broline, B.M. (1977) Regiospecific and stereoselective syntheses of hydroxy-cyclohexyltriphenyltin compounds.J. organometal. Chem. 136: C41-C45.
Fish, R.H. and Broline, B.M. (1978) Selective syntheses and reactions of epoxy-, hydroxy-and keto-substituted cyclohexyltriphenyltin compounds.J. organometal. Chem. 159: 255–278.
Fish, R.H., Casida, J.E. and Kimmel, E.C. (1977) Bioorganotin chemistry: situs and stereoselectivity in the reaction of cyclohexyltriphenyltin with a cytochrome P-450 dependent monooxygenase enzyme system.Tetrahedron Lett. 40: 3515–3518.
Fish, R.H., Casida, I.E. and Kimmel, E.C. (1978) Bioorganotin chemistry: stereo and situ-selectivity in the monooxygenase enzyme reactions of cyclohexyltin compounds.Am. Chem. Soc. Symp. Ser. 82: 82–93.
Graves, J.B., Bradley, J.R. and Bagent, J.L. (1965) Laboratory evaluation of several organotin compounds againstHeliothis spp.J. econ. Ent. 58: 583–584.
Ishaaya, I. and Ascher, K.R.S. (1977) Effect of diflubenzuron on growth and carbohydrate hydrolases ofTribolium castaneum.Phytoparasitica 5: 149–158.
Ishaaya, I., Ascher, K.R.S. and Yablonski, S. (1981) The effect of BAY SIR 8514, diflubenzuron, and Hercules 24108 on growth and development ofTribolium confusum.Phytoparasitica 9: 207–209.
Ishaaya, I. and Casida, J.E. (1975) Phenyltin compounds inhibit digestive enzymes ofTribolium confusum larvae.Pestic. Biochem. Physiol. 5: 350–358.
Ishaaya, I., Holmstead, R.L. and Casida, J.E. (1977) Triphenyl derivatives of group IV elements as inhibitors of growth and digestive enzymes ofTribolium castaneum larvae.Pestic. Biochem. Physiol. 7: 573–577.
Ishaaya, I., Yablonski, S., Ascher, K.R.S. and Casida, J.E. (1980) Triphenyl and tetraphenyl derivatives of group V elements as inhibitors of growth and digestive enzymes ofTribolium confusum andTribolium castaneum larvae.Pestic. Biochem. Physiol. 13: 164–168.
Kimmel, E.C, Casida, J.E. and Fish, R.H. (1980) Bioorganotin chemistry. Microsomal monooxygenase and mammalian metabolism of cyclohexyltin compounds including the miticide cyhexatin.J. agric. Fd Chem. 28: 117–122.
Livingston, J.M., Yearian, W.C. and Young, S.Y. (1978) Insecticidal activity of selected fungicides: effects on three lepidopterous pests of soybean.J. econ. Ent. 71: 111–112.
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Ishaaya, I., Ascher, K.R.S. & Yablonski, S. Differential effect of triphenyltin chloride and its cyclohexyl derivatives on growth and development oftribolium confusum . Phytoparasitica 10, 205–208 (1982). https://doi.org/10.1007/BF02994530
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DOI: https://doi.org/10.1007/BF02994530