Abstract
Through various processes the nitrogen oxides (NOX) interact with trace gases in the troposphere and stratosphere which do absorb in the spectral range relevant to the greenhouse effect (infrared wavelengths). The net effect is an enhancement of the greenhouse effect. The catalytic role of NOX in the production of tropospheric ozone provides the most prominent contribution. The global waming potential is estimated as GWP (NOX = 30 – 33 and 7 – 10 for the respective time horizons of 20 and 100 years, and is thereby comparable to that of methane. NOX emissions in rural areas of anthropogenically influenced regions, or those in the vicinity of the txopopause caused by air traffic, cause the greenhouse effectivity to be substantially more intense. We estimate an additional 5–23 % for Germany’s contribution to the anthropogenic greenhouse effect as a result of the indirect greenhouse effects stemming from NOX. Furthermore, a small and still inaccurately defined amount of the deposited NOX which has primarily been converted into nitrates is again released from the soil into the atmosphere in the form of the long-lived greenhouse gas nitrous oxide (N2O). Thus, anthropogenically induced NOX emissions contribute to enhanced greenhouse effect and to stratospheric ozone depletion in the time scale of more than a century.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
Attmannspacher W.;Hartmannsgruber R.;Lang P.: Langzeittendenzen des Ozons der Atmosphäre aufgrund der 1967 begonnenen Ozonmeßreihen am Meteorologischen Observatorium Hohenpeißenberg. Meteorol. Rdsch.37 (1988) 307–358
Brühl C.: The impact of the future scenarios for methane and other chemically active gases on the GWP of methane. Chemosphere26 (1993) 731 - 738
Brumme R.;Beese F.: Effects of liming and nitrogen fertilization on emissions of CO2 and N2O from a temporate forest. J. Geophys. Res.97 (1992) 12851–12858
Charlson R. J.;Schwartz S. E.;Hales J. M.;Cess R. D.;Coakley J. A.;Hansen J. E.;Hofmann D. J.: Climate forcing by anthropogenic aerosols. Science255 (1992) 423–430
Crutzen P. J.: The role of NO and NO2 in the chemistry of the troposphere and stratosphere. Ann. Rev. Earth Planet. Sci.7 (1978) 443–472
Crutzen P. J.: Atmospheric interactions — homogeneous gas reactions of C, N and S containing compounds. In:Bolin B.;Cook R. B. (eds.): The major biogeochemical cycles and their interactions. SCOPE21 (1983) 67–114
Crutzen P. J.;Schmailzl U.: Chemical budgets of the stratosphere. Planet. Space Sci.31 (1983) 1009–1032
Crutzen P. J.;Zimmermann P.: The changing photochemistry of the troposphere. Tellus 43AB (1991) 136–151
Dasch J. M.: Nitrous oxide emissions from vehicles. J. Air Waste Manage. Assoc.42 (1992) 63–67
Derwent R. G.;Davies T. J.: Modelling the impact of NOX or hydrocarbon control on photochemical ozone in Europe. Atmos. Environ.28 (1994) 2039–2052
Ehhalt D. H.; Drummond J. W.: The tropospheric cycle of NOX. In: Georgii H. W.; Jaeschke W. (eds.): Chemistry of the unpolluted and polluted troposphere. NATO ASI Series C96 (1982) 219–251 Reidel, Dordrecht
Eichner M. J.: Nitrous oxide emissions from fertilised soils: Summary of available data. J. Environ. Qual.19 (1990) 272 - 280
Fuglestvedt J. S.;Jonson J. E.;Isaksen I.S.A.: Effects of reductions in stratospheric ozone on tropospheric chemistry through changes in photolysis rates. Tellus46B (1994) 172–192
Geiss H.; Volz-Thomas A.: Lokale und regionale Ozonproduktion: Chemie und Transport. Abschlußbericht zum Vorhaben BMFT 07EU7235 (1993) (Report from the Jülich research center No. Jül-2764)
Hameed S.;Dignon J.: Global emissions of nitrogen and sulfur oxides in fossil fuel combustion 1970 – 1986. J. Air Waste Manage. Assoc.42 (1991) 159–163
Hauck R. D.: A human ecosphere perspective of agricultural nitrogen cycling. In:Wilson J. R. (ed.): Advances in nitrogen cycling in agricultural ecosystems. CAB International, Wallingford (1988) pp. 3–19
Hauglustaine D. A.;Grainier C.;Brasseur G. P.;Mégie G.: The importance of atmospheric chemistry in the calculation of radiative forcing on the climate system. J.- Geophys. Res.99 (1994) 1173–1186
ICAO International Civil Aviation Organization: ICAO statistical yearbook 1992 (1992a)
ICAO International Civil Aviation Organization: Outlook for air transport to the years 2001, ICAO circular 237-At/96 (1992b)
IPCC Intergovernmental Panel on Climate Change: Climate change — The IPCC scientific assessment (Houghton J. T.;Jenkins G. J.;Ephraums J. J. eds.) (1990) Cambridge University Press, Cambridge
IPCC Intergovernmental Panel on Climate Change: Climate change 1992 — The supplementary report to the IPCC scientific assessment (Houghton J. T.;Callendar B. A.;Varney S. K. eds.) (1992) Cambridge University Press, Cambridge
IPCC Intergovernmental Panel on Climate Change: Radiative forcing of climate — The 1994 report of the scientific assessment working group of IPCC. (1994) Cambridge University Press, Cambridge
Johnson C.;Henshaw J.;McInnes G.: Impact of aircraft and surface emissions of nitrogen oxides on tropospheric ozone and global warming. Nature355 (1992) 69–71
Khalil M. A. K.;Rasmussen R. A.: The global sources of nitrous oxide. J. Geophys. Res.97 (1992) 14651–14660
Keller M.;Kaplan W. A.;Wofsy S. C.;DaCosta J. M.: Emission of N2O from tropical forest soils: Response to fertilization with NH4+NO 3− , and PO43−. J. Geophys. Res.93 (1988) 1600–1604
Kiehl J. T.;Briegleb B. P.: The relative roles of sulfate aerosols and greenhouse gases in climate forcing. Science260 (1993) 311 - 314
Kleinman L.;Lee Y.-N.;Springston S. R.;Nunnermacker L.;Zhou X.;Brown R.;Hallock K.;Klotz P.;Leahy D.;Lee J. H.;Newman L.: Ozone formation at a rural site in the southwestern United States. J. Geophys. Res.99 (1994) 3469–3482
Lin X.;Trainer M.;Liu S. C.: On the nonlinearity of the tropospheric ozone production. J. Geophys. Res.93 (1988) 15879–15888
Liu S. C.;Trainer M.;Fehsenfeld F. C.;Parrish D. D.;Williams E. J.;Fahey D. W.;Huebler G.;Murphy P. C.: Ozone production in the rural troposphere and the implications for regional and global distributions. J. Geophys. Res92 (1987) 4191–4207
Logan J. A.: Nitrogen oxides in the troposphere: Global and regional budgets. J. Geophys. Res.88 (1983) 10785–10807
Luke W. T.;Dickerson R. R.;Ryan W. F.;Pickering K. E.;NunNermacker L. J.: Tropospheric chemistry over the Great Plains of the United States 2. Trace gas profiles and distributions. J. Geophys. Res.97 (1992) 20647–20670
Moussiopoulos N.: Influence of power plant emissions and industrial emissions on the leeward ozone levels. Atmos. Environ.24A (1990) 1451–1460
NRC, National Research Council, Environmental Studies Board: Causes and effects of changes in stratospheric ozone update 1983. National Academy Press, Washington (1984)
Olszyna K. J.;Bailey K. M.;Simonaitis R.;Meagher J. F.: Ozone and NOy relationships at a rural site. J. Geophys. Res.99 (1994) 14557–14563
Penner J. E.;Atherton C. S.;Dignon J.;Ghan S. J.;Walton J. J.;Hameed S.: Tropospheric nitrogen: A three-dimensional study of sources, distributions, and deposition. J. Geophys. Res.96 (1991) 959 - 990
Prinn R. G.: The interactive atmosphere: Global atmosphericbiospheric chemistry. Ambio23 (1994) 50–61
Schmidt J.;Sciler W.;Conrad R.: Emission of nitrous oxide from temperate forest soils into the atmosphere. J. Atmos. Chem.1 (1988) 95–115
Thompson A. M.: The oxidizing capacity of the earth’s atmosphere: Probable past and future changes. Science256 (1992) 1157–1165
Trainer M.;Parrish D. D.;Buhr M. P.;Norton R. B.;Fehsenfeld C.;Anlauf K. G.;Bottenheim J. W.;Tang Y. Z.;Wiebe H. A.;Roberts J. M.;Tanner R. L.;Newman L.;Bowersox V. C.;Meagher J. F.;Olszyna K. J.;Rodgers M. O.;Wang T.;Berresheim H.;Demerjian K. L.;Roychchowddhury U. K.: Correlation of ozone with NOX in photochemically aged air. J. Geophys. Res.98 (1993) 2917–2925
Umwelbundesamt: Daten zur Umwelt 1990/91. Erich Schmidt Verlag, Berlin (1992)
Umwelbundesamt: Jahresbericht 1992. Berlin (1993) 378 pages
Volz A.;Kley D.: Ozone measurements made in the 19th century: An evaluation of the Montsouris series. Nature332 (1988) 240 - 242
Williams E. J.;Hutchinson G. L.;Fehsenfeld F. C.: NOX and N2O emissions from soil. Global Biogeochem. Cycles6 (1992) 351 - 388
WMO, World Meteorological Organization: Scientific assessment of ozone depletion: 1994. WMO/UNEP Global Ozone Research and Monitoring Project. Report No.37, Genf (1995)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lammel, G., Graßl, H. Greenhouse effect of NOX . Environ. Sci. & Pollut. Res. 2, 40–45 (1995). https://doi.org/10.1007/BF02987512
Issue Date:
DOI: https://doi.org/10.1007/BF02987512