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Kinetic constraints on theIn-situ remediation of soils contaminated with organic chemicals

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Abstract

Cleanup of contaminated soils to comply with soil quality limits currently receives much interest.In-situ remediation of contaminated soils relies on the ability of the techniques employed to enhance the rate of release of contaminants from the soil-sorbed and nonaqueous phase liquid (NAPL) phases into the aqueous or gaseous phases from which they can be more readily removed and treated. Contaminant concentrations in these “environmentally mobile” forms usually decline over time so that the economic efficiency and the overall success of remediation technologies are subject to the “law of diminishing returns”. In this paper we consider the “state of the art” in our understanding of NAPL dissolution and transport, desorption of soilsorbed contaminants and fluid flow in porous media. The extent to which these processes may constrain the success of bioremediation, pump-and-treat remediation and soil venting in relation to established soil quality limits is addressed. Finally, we suggest directions for future research and comment on legislative considerations.

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References

  • Alexander, M.: Biodegradation and bioremediation, Academic Press, San Diego 1994, pp. 302

    Google Scholar 

  • Beck, A. J.;S. C. Wilson;R. E. Alcock;K. C. Jones: Kinetic constraints on the remediation of soils contaminated with organic chemicals: implications for soil quality limits. Crit. Rev. Environ. Sci. Technol. 25, 1–43 (1995)

    CAS  Google Scholar 

  • Beck, A. J.;A. E. Johnston;K. C. Jones: Movement of Nonionic Organic Chemicals Through Agricultural Soils. Crit. Rev. Environ. Sci. Technol. 23, 219–248 (1993)

    Google Scholar 

  • Beck, A. J.;K. C. Jones: Natural Organic Substances and Contaminant Behaviour: Progress, Conflicts and Uncertainties In:A. J. Beck, K. C. Jones, M. H. B. Hayes andU. Mingelgrin, U. Eds. Organic Substances in Soil and Water, Royal Society of Chemistry, Cambridge, UK. pp 184–194 (1993)

    Google Scholar 

  • Bellandi, R. Ed.: Hazardous Waste Site Remediation the engineer’s perspective, Van Nostrand Reinhold, New York 1988, pp. 422

    Google Scholar 

  • Benson, R. C.: Geophysical techniques for subsurface site characterisation. In:D. E. Daniel Ed., Geotechnical Practices for Waste Disposal, Chapman & Hall, London 1993, pp. 311 -357

    Google Scholar 

  • Beven, K. J.;P. Germann: Macropores and Water Flow in Soils. Water Resourc. Res. 18, 1311–1325 (1982)

    Article  Google Scholar 

  • Borden, R. C.;C. M. KaO: Evaluation of groundwater extraction for remediation of petroleum contaminated groundwater. Water Environ. Res. 64, 28–36 (1992)

    CAS  Google Scholar 

  • Bouchard, D. C.;A. L. Wood;M. L. Campbell;P. Nkedi-Kizza;P. S. C. Rao: Sorption nonequilibrium during solute transport. J. Contam. Hydrol. 2, 209–223 (1988)

    Article  CAS  Google Scholar 

  • Bouma, J.: Using Morphometric Expressions for Macropores to improve Soil Pyhsical Analyses of Field Soils. Geoderma. 46, 3–11 (1990)

    Article  Google Scholar 

  • Brusseau, M. L.: Nonequilibrium transport of organic chemicals: the impact of pore-water velocity. J. Contam. Hydrol. 9, 353–368 (1992)

    Article  CAS  Google Scholar 

  • Brusseau, M. L.;R. E. Jessup;P. S. C. Rao: Nonequilibrium Sorption of Organic Chemicals: Elucidation of Rate — Limiting Processes. Environ. Sci. Technol. 25, 134–142 (1991 a)

    Article  CAS  Google Scholar 

  • Brusseau, M. L.;T. Larsen;T. H. Christensen: Rate-limited sorption and nonequilibrium transport of organic chemicals in low organic carbon aquifer materials. Water Resourc. Res. 27, 1137–1145 (1991 b)

    Article  CAS  Google Scholar 

  • Brusseau, M. L.;P. S. C. Rao: Sorption Nonideality During Organic Contaminant Transport in Porous Media. CRC Crit. Rev. Environ. Control 1, 33–99 (1989)

    Google Scholar 

  • Calderbank, A.: The Occurrence and Significance of Bound Pesticide Residues in Soil. Rev. Environ. Contam. Toxicol. 108, 71–103 (1989)

    CAS  Google Scholar 

  • Chiou, C. T.;L. J. Peters;V. H. Freed: A physical Concept of Soil-Water Equilibria for Nonionic Organic Compounds. Science 206, 831–832 (1979)

    Article  CAS  Google Scholar 

  • Chiou, C. T.;P. E. Porter;D. W. Schmedding: Partition Equilibria of Nonionic Organic Compounds between Soil Organic Matter and Water. Environ. Sci. Technol.17, 227–231 (1983)

    Article  CAS  Google Scholar 

  • Chung, A-Y;B. J. McCoy;K. M. Scow: Criteria to Assess When Biodegradation is Kinetically Limited by Intraparticle Diffusion and Sorption. Biotech. Bioeng.41, 625–632 (1993)

    Article  CAS  Google Scholar 

  • Clarke, A. C.;R. D. Norris;D. J. Wilson: Saturated zone remediation of VOCs through sparging. In:D. J. Wilson andA. N. Clarke Eds., Hazardous Waste Site Soil Remediation, Marcel Dekker, New York 1994b, pp. 433–455

    Google Scholar 

  • Clarke, J. H.;D. D. Rieble;R. D. Mutch Jr: Contaminant transport and behaviour in the subsurface. In:D. J. Wilson andA. N. Clarke Eds., Hazardous Waste Site Soil Remediation, Marcel Dekker, New York 1994a, pp. 1–49

    Google Scholar 

  • Cline, P.V.;J. J. Delfino;P. S. C. Rao: Partitioning of aromatic constituents into water from gasoline and other complex solvent mixtures. Environ. Sci, Technol.25, 914–920 (1991)

    Article  CAS  Google Scholar 

  • Dhawan, S.;L. T. Fan;L. E. Erickson;P. Tuitemwong: Modeling, Analysis and Simulation of Bioremediation in Soil Aggregates. Environ. Prog.10, 251–260 (1991)

    Article  CAS  Google Scholar 

  • Donaldson, S. G.;G. C. Miller;W. W. Miller: Remediation of gasoline-contaminated soil by passive volatilisation. J. Environ. Qual.21, 94–102 (1992)

    Article  CAS  Google Scholar 

  • Dzombak, D. A.;P. A. Labieniec;R. L. Siegrist: The need for Uniform Soil Cleanup Coals. Environ. Sci. Technol.27, 765–766 (1993)

    Article  Google Scholar 

  • Efroymson, R. A.;M. Alexander: Reduced mineralization of low concentrations of phenanthrene because of sequestering in nonaqueous-phase liquids. Environ. Sci. Technol.29, 515–521 (1995)

    Article  CAS  Google Scholar 

  • Freeman, H. M., P. R. Sferra, Eds.: Innovative Hazardous Waste Technology Series. Technomic, Lancaster PA 1990

    Google Scholar 

  • Führ, F.;W. Steffens;W. Mittelstaedt B. Brumhard: Pesticides in the Soil — Lysimeter Experiments with 14C-Labelled Active Ingredients. Revised Offprint (1990) from the Annual Report 1989-Research Centre Jülich, Germany (1989)

    Google Scholar 

  • Führ, F.; W. Steffens; W. Mittelstaedt; B. Brumhard: Lysimeter Experiments with 14C-Labelled Pesticides — An Agroecosystem Approach Pest. Chem. 37–47 (1991)

  • Geller, J. T.;J. R. Hunt: Mass transfer from nonaqueous phase liquids in water-saturated porous media. Water Resourc. Rs.29, 833–846(1993)

    Article  CAS  Google Scholar 

  • Glass, R. J.;T. S. Steenhuis;J-Y Parlange: Wetting Front Instability as a Rapid and Far Reaching Hydrological Process. J. Contam. Hydrol.3, 207–226 (1987)

    Article  Google Scholar 

  • Glass, R. J.; G. H. Oosting; T. S. Steenhuis: Preferential Solute Transport in Layered Homogenous Sands as a Consequence of Wetting Front Instability (unpublished manuscinpt)

  • Guerin, W. F.;S. A. Boyd: Diferential Bioavailability of Soil-Sorbed Naphthalene to Two Bacterial Species. Appl. Environ. Microbiol.58, 1142–52(1992)

    CAS  Google Scholar 

  • Harvey, R. W.;S. P. Garabedian: Use of colloid filtration theory in modelling the movement of bacteria through a contaminated sandy aquifer. Environ. Sci. Technol.25, 178–185 (1991)

    Article  CAS  Google Scholar 

  • Hillel, D.;R. S. Baker: A Descriptive Theory of Fingering During Infiltration into Layered Soil. Soil Sci.146, 51 -56 (1988)

    Article  Google Scholar 

  • Hoag, G. E.;B. Cliff: The use of the soil venting technique for the remediation of petroleum-contaminated soils. In:E. J. Calabrese andP. T. Kostechi Eds., Soils Contaminated by Petroleum: Environmental and Public Health Effects, Wiley, New York 1988, pp. 301–316

    Google Scholar 

  • Hoeppel, R. E.;R. E. Hinchee: Enhanced biodegradation for on-site remediation of contaminated soils and groundwater. In:D. J. Wilson andA. N. Clarke Eds., Hazardous Waste Site Soil Remediation, Marcel Dekker, New York 1994, pp. 309–431

    Google Scholar 

  • Imhoff, P. T.;P. R. Jaffe;G. F. Pinder: An experimental study of complete dissolution of a nonaqueous phase liquid in saturated porous media Water Resourc. Res.30, 307–320 (1994)

    Article  CAS  Google Scholar 

  • Jones, K. c.;J. A. Sratford;P. Tidridge;K. S. Waterhouse;N. B. Vogt: Organic Contaminants in Welsh Soils: Polynudear Aromatic Hydrocarbons. Environ. Sci. Technol.23 540–550 (1989)

    Article  CAS  Google Scholar 

  • Kaufman, D. D.;G. G. Still;G. D. Paulson;S. K. Bandal: Bound and Conjugated Pesticide Residues. ACS Symp. Ser. 29. Am. Chem. Soc. Washington D.C. (1976)

    Google Scholar 

  • Kent, B.;P. Mann: Recovery well systems. In:D. E. Daniel Ed., Geotechnical Practices for Waste Disposal, Chapman & Hall, London 1993, pp. 497–519

    Google Scholar 

  • Kung, K-J. S.: Preferential Flow in A Sandy Vadoze Zone: I. Field Observations. Georderma.46, 51 -58 (1990a)

    Article  Google Scholar 

  • Kung, K-J. S.: Preferential Flow in A Sandy Vadoze Zone: II. Mechanisms and Implications. Geoderma.46 59–71 (1990 b)

    Article  Google Scholar 

  • Labare, M. P.;M. Alexander: Enhanced mineralization of organic compounds in nonaqueous-phase liquids. Environ. Toxicol. Chem.14, 257–265 (1995)

    Article  CAS  Google Scholar 

  • Lee, L. S.;M. Hagwall;J. J. Delfino;P. S. C. Rao: Equilibrium partitioning of polycyclic aromatic hydrocarbons from diesel fuel into water. Environ. Sci. Technol.26 2104–2109 (1992 a)

    Article  CAS  Google Scholar 

  • Lee, L. S.;M. Hagwall;J. J. Delfino;P. S. C. Rao: Equilibrium partitioning of polycyclic aromatic hydrocarbons from coal tar into water. Environ. Sci. Technol.26, 2110–2115 (1992 b)

    Article  CAS  Google Scholar 

  • Lee, L. S.;P. S. C. Rao;M. L. Brusseau;R. A. Ogwada: Nonequilibrium Sorption of organic chemicals during flow trough columns of aquifer material. Environ. Toxicol. Chem. 7, 779–793 (1988)

    Article  CAS  Google Scholar 

  • Lewis, R. F.: Site Demonstration of Slurry-Phase Biodegradation of PAH Contaminated Soil. J. Air & Waste Man. Assoc.43, 503–508 (1993)

    CAS  Google Scholar 

  • Loehr, R. C.: Bioremediation of soils. In:D. E. Daniel Ed., Geotechnical Practices for Waste Disposal, Chapman & Hall, London 1993, pp. 520–550

    Google Scholar 

  • Luthy, R. G.;D. A. Dzombak;C. A. Peters;S. B. Roy;A. Ramaswami;D. V. Nakles;B. R. Nott: Remediating tarcontaminated soils at manufactured gas plant sites. Environ. Sci. Technol.28, 266 a-276 a (1994)

    CAS  Google Scholar 

  • MacDonald, J. A.;M. C. Kavannaugh: Restoring contaminated groundwater: an achievable goal? Environ. Sci. Technol.28, 362 a-368 a (1994)

    Article  CAS  Google Scholar 

  • Mackay, D. M. andJ. A. Cherry: Groundwater Contamination: Pump-and-Treat Remediation. Environ. Sci. Technol.23, 630–636 (1989)

    Article  CAS  Google Scholar 

  • Marley, M. C.; G. E. Hoag: Induced soil venting for the recovery/restoration of gasoline hydrocarbons in the vadoze zone. Presented at the NWAA/API Conference, Petroleum Hydrocarbons and Organic Chemicals in Groundwater, Houston, Nov. 5 – 7 1984 (cited in Hoag and Cliff, 1988)

  • Meer, J. R. van der: Potential and limitations to the use of Microbiological methods for the treatment of environmental pollution EAWAG News36, pp. 20–24 (1994)

    Google Scholar 

  • Mihelcic, J. R.;R. G. Luthy: Sorption and microbial degradation of naphthalene in soil-water suspensions under denitrification conditions. Environ. Sci. Technol.25, 169–177 (1991)

    Article  CAS  Google Scholar 

  • Miller, C. T.;M. M. Poirier-McNeill;A. S. Mayer: Dissolution of trapped nonaqueous phase liquids: mass transfer characteristics. Water Resourc. Res.26, 2783–96 (1990)

    Google Scholar 

  • Mingelgrin, U.;Z. J. Gerstl: Re-evaluation of Partitioning as a Mechanism of Nonionic Chemicals Adsorption in Soils. J. Environ. Qual.12, 1–11 (1983)

    CAS  Google Scholar 

  • Murarka, I. P.: J. Hazard. Mater.32, 6–13 (1992) cited in Luthy et al. 1994

    Article  Google Scholar 

  • National research council: Alternatives for groundwater cleanup. National Academy Press, Washington DC (1994)

    Google Scholar 

  • Nielsen, D. R.;J. W. Biggar: Miscible displacement in soils: I. experimental information. Soil Sci. Soc. A Proc.25, 1–6 (1961)

    Google Scholar 

  • Ogram, A. V.;R. E. Jessup;L. T. Ou;P. S. C. Rao: Effects of Sorption on Biological Degradation Rats of Acetic Acid in Soils. Environ. Microbiol.49, 582–587 (1985)

    CAS  Google Scholar 

  • Pederson, T. A.; J. T. Curtis: Soil Vapor Extraction Technology Reference Handbook. U.S. EPA Report EPA/540/2-91/003. U.S. Environmental Protection Agency, Risk Reduction Engineering Laboratory, Edison, New Jersey

  • Pignatello, J. J.: Sorption Dynamics of Organic Chemicals in Soils and Sediments In:B. L. Sawhney andK. Brown, Eds. Reactions and Movement of Organic Chemicals in Soils. Soil Sci. Soc. Am. Inc., Am. Soc. Agron. Inc., Madison, Wisconsin pp. 271–304 (1989)

    Google Scholar 

  • Pignatello, J. J.: Recent Advances in Sorption Kinetics In:A. J. Beck, K. C. Jones, M. H. B. Hayes andU. Mingelgrin, U. Eds. Organic Substances in Soil and Water, Royal Society of Chemistry, Cambridge, UK. PP 128–140 (1993)

    Google Scholar 

  • Powers, S. E.;L. M. Abriola;W. J. Weber Jr.: An experimental investigation of nonaqueous phase liquid dissolution in saturated subsurface systems: steady mass transfer rates. Water Resourc. Res.28, 2691–2706 (1992)

    Article  CAS  Google Scholar 

  • Powers, S. E.;L. M. Abriola;W.J. Weber Jr: An experimental investigation of nonaqueous phase liquid dissolution in saturated subsurface systems: transient mass transfer rates. Water Resourc. Res.30, 321–332 (1994)

    Article  CAS  Google Scholar 

  • Riggs, C. O.: Soil exploration at contaminated sites. In:D. E. Daniel Ed., Geotechnical Practices for Waste Disposal, Chapman & Hall, London 1993, pp. 358–378

    Google Scholar 

  • Rijnaarts, H. H. M.;A. Bachman;J. C. Jumelet;A. J. B. Zhender: Effect of Desorption and Intraparticle Mass Transfer on the Aerobic Biomineralization of Hexachlorocyclohexane in a Contaminated Calcareous Soil. Environ. Sci. Technol.24, 1349–1354 (1990)

    Article  CAS  Google Scholar 

  • Rippen, G.;T. Held;P. Ripper: Microbiological remediation of wasteoil polluted soilsecotoxicological and toxicological considerations. Environ. Sci. Pollut. Res.1, 185–189 (1994)

    Article  Google Scholar 

  • Roy, S. B.;D. A. Dzombak;M. A. Ali: Assessment of in-situ solvent extraction for remediation of coal tar sites — column studies. Water Environ. Res.67, 4–15 (1995)

    Article  CAS  Google Scholar 

  • Sawhney, B. L.;J. J. Pigntello;S. M. Steinberg: Determination of 1,2-dibromoethane (EDB) in field soils: implications for volatile organic compounds. J. Environ. Qual.17, 149–152 (1988)

    Article  CAS  Google Scholar 

  • Schwarzenbach, R. P.;J. Westall: Transport of Nonpolar Organic Compounds from Surface Water to Groundwater. Environ. Sci. Technol.15, 1360–1367 (1981)

    Article  CAS  Google Scholar 

  • Scow, K. M.;M. Alexander: Effects of Diffusion on the Kinetics of Biodegradation: Experimental Results with Synthetic Aggregates. Soil Sci. Soc. Am. J.56, 1128–134 (1992)

    Google Scholar 

  • Scow, K. M.;J. L. Hutson: Effects of Diffusion and Sorption on the Kinetics of Biodegradation: Theoretical Considerations. Soil Sci. Soc. Am. J.56, 119–127 (1992)

    CAS  Google Scholar 

  • Seagren, E. A.;B. E. Rittmann;A. J. Valocchi: Quantitative evaluation of the enhancement of NAPL-pool dissolution by flushing and biodegradation. Environ. Sci. Technol.28, 833–839 (1994)

    Article  CAS  Google Scholar 

  • Sims, R. C.: Soil remediation techniques at uncontrolled hazardous waste sites: a critical review. J. Air Waste Manage. Assoc.40, 704–712 (1990)

    CAS  Google Scholar 

  • Steinberg, S. M.;J. J. Pignatelle;B. J. Sawhney: Persistence of 1,2-Dibromoethane in Soils: Entrapment in Inraparticle Micropores. Environ. Sci. Technol.21, 1201–1207 (1987)

    Article  CAS  Google Scholar 

  • Subba-Rao, R. V.;M. Alexander: Effect of Sorption on mineralization of low concentrations of aromatic compounds in lake water samples. Appl. Environ. Microbiol.44, 659–668 (1982)

    CAS  Google Scholar 

  • Travis, C. C.;J. M. McInnis: Vapor extraction of organics from subsurface soils. Environ. Sci. Technol.26, 1885–1887 (1992)

    Article  CAS  Google Scholar 

  • Wehrle, K.: Soil vapor extraction (SVE): limitations. In:F. Arendt, G. J. Annokkee, R. Bosman andW. J. von den Brink Eds., Contaminated Soil’93, Vol 2, Kluwer, Dordrecht 1993, pp. 1463–1465

    Google Scholar 

  • Wilson, D. J.;A. N. Clarke: Soil vapor stripping. In:D. J. Wilson andA. N. Clarke Eds., Hazardous Waste Site Soil Remediation, Marcel Dekker, New York 1994, pp. 171–242

    Google Scholar 

  • Wu, S.;P M. Gschend: Sorption Kinetics of Hydrophobie Organic Compounds to Natural Sediments and Soils. Environ. Sci. Technol.20, 717–725 (1986)

    Article  CAS  Google Scholar 

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  1. Division of Environmental Sciences, Institute of Environmental and Biological Sciences, Lancaster University, LA1 4YQ, Lancaster, UK

    Angus J. Beck & Kevin C. Jones

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  1. Angus J. Beck
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Beck, A.J., Jones, K.C. Kinetic constraints on theIn-situ remediation of soils contaminated with organic chemicals. Environ. Sci. & Pollut. Res. 2, 244–252 (1995). https://doi.org/10.1007/BF02986778

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