Skip to main content
Log in

Speciation analysis of organotin compounds in lard poisoning accident in Jiangxi Province, China

  • Published:
Science in China Series B: Chemistry Aims and scope Submit manuscript

Abstract

Samples including organotin contaminated lard, urine, blood, and main organs of the poisoned bodies were collected in the incident which took place in Longnan and Dingnan counties, Jiangxi Province, China around the new year’s day of 1999. The organotin compounds in these samples were identified and determined by gas chromatography-flame photometric detector (GC-FPD), gas chromatography-mass spectroscopy (GC-MS) and inductively coupled plasma- mass spectroscopy (ICP-MS). Experiments confirmed that tri- and dimethyltin are the main components that caused the poisoning accident. Monomethyltin, dioctyltin and inorganic tin were also found in several samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zhou, Q. F., Jiang, G. B., Qi, D. Y., Synthesis of propylmagnesium bromide Grignard reagent and its application of butyltin compounds, Anal. Chem., 1999, 27(10): 1197.

    CAS  Google Scholar 

  2. Jiang, G. B., Xu, F. Z., Analysis of butyltin species in water by gas chromatography with flame photometric detection using quartz surface-induced tin emission, Appl. Organomet. Chem., 1996, 10(2): 77.

    Article  CAS  Google Scholar 

  3. Jiang, G. B., Ceulemans, M., Adams, F. C., Optimization study for the speciation analysis of organotin and organogermanium compounds by on-column capillary gas chromatography with flame photometric detection using quartz surfaceinduced luminescence, J. Chromatogr., 1996, 727(1): 119.

    Article  CAS  Google Scholar 

  4. Clark, S., Ashby, J., Craig, P. J., On-column hydride generation method for the production of volatile hydrides of tin arsenic and antimony for the gas Chromatographie analysis of dilute solutions, Analyst, 1987, 112(12): 1781.

    Article  CAS  Google Scholar 

  5. Cai, Y., Rapsomanikis, S., Andreae, M. O. et al., Determination of butyltin compounds in sediments using gas chromato- graphy-atomic absorption spectrometry: Comparison of sodium tetrahydroborate and sodium tetraethylborate derivatization methods, Anal. Chim. Acta, 1993, 274(2): 243.

    Article  CAS  Google Scholar 

  6. Stab, J. A., van Hattum, B., de Voogt, P. et al., Preparation of pentylated organotin standards for use in trace analysis with gas chromatography, Mikrochim. Acta, 1992, 109(1–4): 101.

    CAS  Google Scholar 

  7. Abalos, M., Bayona, J. M., Compano, R. et al., Analytical procedures for the determination of organotin compounds in sediment and biota: a critical review, J. Chromatogr. A, 1997, 788(1+2):1.

    Article  CAS  Google Scholar 

  8. Jiang, G. B., Maxwell, P. S., Siu, K. W. M. et al., Determination of butyltin in mussel by gas chromatography with flame photometric detection using quartz surface-induced luminescence, Anal. Chem., 1991, 63(15): 1506.

    Article  CAS  Google Scholar 

  9. Snoeij, N. J., Penninks, A. H., Seinen, W., Biological activity of organotin compounds—An overview, Environ. Research, 1987, 44(2):335.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiang Guibin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jiang, G., Zhou, Q., He, B. et al. Speciation analysis of organotin compounds in lard poisoning accident in Jiangxi Province, China. Sc. China Ser. B-Chem. 43, 531–539 (2000). https://doi.org/10.1007/BF02969499

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02969499

Keywords

Navigation