Abstract
In micro- and nanoflows, the Boltzmann distribution is valid only when the electric double layers (EDL’s) are not overlapped and the ionic distributions establish an equilibrium state. The present study has numerically investigated unsteady two-dimensional fully-developed electroosmotic flows between two parallel flat plates in the nonoverlapped and overlapped EDL cases, without any assumption of the Boltzmann distribution. For the study, two kinds of unsteady flows are considered: one is the impulsive application of a constant electric field and the other is the application of a sinusoidally oscillating electric field. For the numerical simulations, the ionic-species and electric-field equations as well as the continuity and momentum ones are solved. Numerical simulations are successful in accurately predicting unsteady electroosmotic flows and ionic distributions. Results show that the nonoverlapped and overlapped cases are totally different in their basic characteristics. This study would contribute to further understanding unsteady electroosmotic flows in micro- and nanofluidic devices.
Similar content being viewed by others
Abbreviations
- C s ,C 0 :
-
Molar ionic concentrations
- D s ,D :
-
Ionic diffusion coefficients
- E i ,E 0 :
-
External electric fields
- e f :
-
External electric-field mode
- F :
-
Faraday constant
- H(t) :
-
Heaviside function
- h :
-
Channel half-width
- k :
-
Parameter
- M :
-
Grid resolution
- p :
-
Pressure
- R :
-
Gas constant
- Sc :
-
Schmidt number
- T :
-
Absolute temperature
- t :
-
Time
- U c ,U 0 :
-
Streamwise velocities
- U eo :
-
Electroosmotic velocity
- u i ,(u,v) :
-
Velocity components
- x i , (x, y):
-
Cartesian coordinates
- y’:
-
Normal distance from surface
- Z s ,z :
-
Ionic valences
- Δt :
-
Transient timescale
- Δt c ,Δ te :
-
Transient timescales
- Δtu,Δtω :
-
Transient timescales
- δ:
-
Penetration depth
- δ(y):
-
Dirac delta function
- ε:
-
Fluid permittivity
- ξ0 :
-
Zeta potential
- ξ0 * :
-
Nondimensional zeta potential
- κ:
-
Nondimensional EDL length
- λ:
-
EDL length
- ν:
-
Fluid kinematic viscosity
- ξ:
-
Parameter
- ρ:
-
Fluid density
- ρe :
-
Volumetric electric-charge density
- σ0 :
-
Surface electric-charge density
- Ψ,Ψw :
-
Electric potentials
- ω:
-
External electric-field frequency
- •:
-
Spatial averaging
- i :
-
Indices
- m :
-
Anions
- p :
-
Cations
- s :
-
Indices (p, m)
References
Currie, I. G., 1974,Fundamental Mechanics of Fluids, McGraw-Hill, New York.
Dose, E. V. and Guiochon, G., 1993, “Timescales of Transient Processes in Capillary Electrophoresis,”Journal of Chromatography A, Vol. 652, pp. 263–275.
Dutta, P. and Beskok, A., 2001, “Analytical Solution of Time Periodic Electroosmotic Flows: Analogies to Stokes’ Second Problem,”Analytical Chemistry, Vol. 73, pp. 5097–5102.
Erickson, D. and Li, D., 2003, “Analysis of Alternating Current Electroosmotic Flows in a Rectangular MicroChannel,”Langmuir, Vol. 19, pp. 5421–5430.
Hu, L., Harrison, J. D., and Masliyah, J. H., 1999, “Numerical Model of Electrokinetic Flow for Capillary Electrophoresis,”Journal of Colloid and Interface Science, Vol. 215, pp. 300–312.
Kwak, H. S. and Hasselbrink Jr., E. F., 2005, “Timescales for Relaxation to Boltzmann Equilibrium in Nanopores,”Journal of Colloid and Interface Science, Vol. 284, pp. 753–758.
Li, D., 2004,Electrokinetics in Microfluidics, Elsevier, London.
Lin, H., Storey, B. D., Oddy, M. H., Chen, C. -H. and Santiago, J. G., 2004, “Instability of Electrokinetic MicroChannel Flows with Conductivity Gradients,”Physics of Fluids, Vol. 16, pp. 1922–1935.
Oddy, M. H., Santiago, J. G. and Mikkelsen, J. C., 2001, “Electrokinetic Instability Micromixing,”Analytical Chemistry, Vol. 73, pp. 5822–5832.
Qian, S. and Bau, H. H., 2005, “Theoretical Investigation of Electro-osmotic Flows and Chaotic Stirring in Rectangular Cavities,”Applied Mathematical Modelling, Vol. 29, pp. 726–753.
Qu, W. and Li, D., 2000, “A Model for Overlapped EDL Fields,”Journal of Colloid and Interface Science, Vol. 224, pp. 397–407.
Söderman, O. and Jönsson, B., 1996, “Electroosmosis: Velocity Profiles in Different Geometries with Both Temporal and Spatial Resolution,”Journal of Chemical Physics, Vol. 105, pp. 10300–10311.
Stone, H. A., Stroock, A. D. and Ajdari, A., 2004, “Engineering Flows in Small Devices: Microfluidics toward a Lab-on-a-Chip,”Annual Review of Fluid Mechanics, Vol. 36, pp. 381–411.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kang, S., Suh, Y.K. Unsteady electroosmotic channel flows with the nonoverlapped and overlapped electric double layers. J Mech Sci Technol 20, 2250–2264 (2006). https://doi.org/10.1007/BF02916342
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02916342