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  • Solid State Reactions
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Metallurgical Transactions B Aims and scope Submit manuscript

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Abbreviations

c i :

CO2 concentration at reaction interface, mole/cm3

c e :

equilibrium CO2 concentration, mole/cm3

c o :

bulk CO2 concentration, mole/cm3

D e :

effective diffusivity of CO2 through oxide shell, cm2/s

h T :

total heat transfer coefficient, cal/(cm2)(s)(°C)

k c :

rate constant of interfacial reaction, g CaCO3/(cm2)(s)(atm)

k e :

effective thermal conductivity of oxide shell, cal/(cm)(s)(°C)

k g :

film coefficient of mass transfer, cm/s

M :

molecular weight of CaCO3, g/mole

m th :

thermal mass, cal/°C

\(\dot n\) :

rate of reaction, mole/s

p eCO2 :

equilibrium partial pressure of CO2, atm

r i :

radius of reaction interface, cm

r o :

particle radius, cm

r * :

=r i r o

T G :

gas temperature, K

T i :

temperature at reaction interface, K

w :

weight of limestone, g

∈CaO:

porosity of decomposed oxide shell

ϕ:

time, s

ρ:

density, g/cm3

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Asaki, Z., Fukunaka, Y. & Kondo, Y. Authors' reply. Metall Trans B 6, 482–484 (1975). https://doi.org/10.1007/BF02913837

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