Abstract
A new hexanuclear manganese (III) azametallacrown, [Mn6 (anhz)6 (DMF)2 (H2O)4]·8DMF was synthesized using trianionic pentadentate ligand, N-acetyl-3-hydroxy-2-naphthoic acid hydrazide (anhz3−), and characterized by X-ray single crystal diffraction. The deprotonated ligand bridges the metal ions using the N−N group of hydrazide to form an 18-membered-ring that has M−N−N repeating units and a cavity in the center. The stereochemistry of the compound has an alternating Δ/Λ propeller configuration.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Whiteford J A, Lu C V, Stang P J. Molecular Architecture via Coordination: Self-Assembly, Characterization, and Host-Guest Chemistry of Mixed, Neutral-Charged, Pt−Pt and Pt−Pd Macrocyclic Tetranuclear Complexes. X-ray Crystal Structure of Cyclobis [[cis-Pt (dppp) (4-Ethylpyridine)2][cis-Pd2+ (Pet3)2−]OSO2CF3]].J Am Chem Soc, 1997,119: 2524.
Stang P T, Cao D H, Sito S,et al. Self-Assembly of Cationic, Tetranuclear, Pt(II) and Pd(II) Macrocyclic Squares. X-ray Crystal Structure of [Pt2+ (dppp) (4,4′-Bipyridyl)2− OSO2CF3]4.J Am Chem Soc, 1994,117: 6273.
Pecoraro V L, Stemmler A J, Gibney B R,et al. Progress in Inorganic Chemistry, Vol. 45. New York: Wiley. 1997. 83–177.
Lah M S, Pecoraro V L. Isolation and Characterization of {Mn(II)[Mn(III) (Salicylhydroximate)]4 (Acetate)2 (DMF)6}· 2DMF: An Inorganic Analogue of M2+ (12-Crown-4).J Am Chem Soc, 1998,111: 7258.
Lah M S, Kirk M L, Hatfield W,et al. The Tetranuclear Cluster FeIII [FeIII (Salicylhydroximato) (MeOH) (Acetate)]3 is an Analogue of M3+ (9-Crown-3).J Chem Soc Chem Commun, 1989, 1606.
Pecoraro V L. Structural Characterization of [VO(salicylhydroximate) (CH3OH)]3: Applications to Brain, the Biochemistry of Vanadium (V).Inorg Chim Acta, 1989,155:171.
Gibney B R, Stemmler A J, Pilotek S,et al. Generalizing the Metallacrown Analogy: Ligand Variation and Solution Stability of the VV 9-Metallacrown-3 Structure Type.Inorg Chem, 1993,32: 6008.
Gibney B R, Wang Hsin, Kampf J W,et al. Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 Structural Type.Inorg Chem, 1996,35: 6184.
Lah M S, Pecoraro V L. A Functional Analogy between Crown Ethers and Metallacrowns.Inorg Chem, 1991,30: 878.
Gibney B R, Kessissoglou D P, Kampf J W,et al. Copper (II) 12-Metallacrown-4: Synthesis, Structure, Ligand Variability and Solution Dynamics in the 12-MC-4 Structural Motif.Inorg Chem, 1994,33: 4840.
Halfen J A, Bodwin J J, Pecoraro V L. Preparation and Characterization of Chiral 12-Metallacrown-4 Complex, Inorganic Analogues of Tetraphenylponyrinatocopper (II).Inorg Chem, 1998,37: 5416.
Stemmler A J, Kampf J W, Pecoraro V L. Synthesis and Crystal Structure of First Inverse 12-Metallacrown-4 Complexes.Inorg Chem, 1995,34: 2271.
Psomas G, Dendrinou-Samara C, Alexiou M,et al. First Fused Dimer Metallacrown Ni II2 (mcp)2(CH3OH)(H2O)\(\left[ {12 - MC Ni_{N\left( {shi} \right)_2 \left( {pko} \right)_2 }^{II} - 4} \right]\left[ {12 - MC Ni_{N\left( {shi} \right)_3 \left( {pko} \right)}^{II} - 4} \right].\) Inorg Chem, 1998,37: 6556.
Lah M S, Gibney B R, Tierney D L,et al. The Fused Metallacrown Anion Na2{[Na0.5[Ga(Salicylhydroximate)4]2 (μ2-OH)4]−}: Is it an Inorganic Analogue of a Cryptate.J Am Chem Soc, 1993,115: 5857.
Kessissoglou D P, Kampf J W, Pecoraro V L. Compositional and Geometrical Isomers of 15-Metallacrown-5 Complexes.Polyhedron, 1994,13: 1379.
Kwak B, Rhee H, Park S,et al. Synthesis and Characteration of [Mn III6 (N-Formylsalicylhydrazidate)6 (MeOH)6]: A New Type of Macrocyclic Hexanuclear Manganese Cluster.Inorg Chem, 1998,37: 3599.
Lin Shen, Liu Shi-xiong, Lin Bi-zhou. Synthesis, Crystal Structure, and Magnetic Properties of a Novel Iron(III) 18-Azametallacrown-6 Compound.Inorg Chim Acta, 2002,328: 69.
Kwak B, Rhee H, Lah M S. Hexanuclear Manganese Metallamacrocycles with Tripled Hydrophobic Tails.Polyhedron, 2000,19:1985.
Kim I, Kwak B, Lah M S. A Series of nanometer-sized hexanuclear Co- Fe- and Ga-metallamacrocycles.Inorg Chim Acta, 2001,317:12.
Liu Shi-xiong, Lin Shen, Lin Bi-zhou,et al. [30] Metallacrown-10 Compounds: [Mn(C14H9N2O3)(CH3OH)10]· 5CH2Cl2·16CH3OH·H2O and [Fe(C14H9N2O3)(CH3 OH)10] 3CH2Cl2·12.5CH3OH·5H2O.Angew Chem Int Ed Engl, 2001,40: 1084.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Supported by the National Natural Science Foundation of China (20171035), The Natural Science Foundation of Hubei Province
Biography: Han Dong-dong (1977-), female, Master, research direction: inorganic chemistry
Rights and permissions
About this article
Cite this article
Dong-dong, H., Gong-zhen, C., Zhen-ping, J. et al. Synthesis and X-ray crystal structure of a new manganese 18-metallacrown-6. Wuhan Univ. J. Nat. Sci. 9, 93–98 (2004). https://doi.org/10.1007/BF02912726
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02912726