Abstract
The technique for preparing phenol formaldehyde resin from phenolated wood (PWF) and its characters were studied and analyzed. Poplar (Populus spp) wood meal was liquefied by phenol in the presence of sulfuric acid as a catalyst. After the liquefied products were cooled, alkaline catalyst and formaldehyde were added. The mixture was kept at (60±2)°C for 1h and then was heated to (85±2)°C for 1h. The influence of molar ratio of formaldehyde to phenol (F/P) was investigated. The results showed when the molar ratio of formaldehyde to phenol was over 1.8, the PWF adhesives had high bond quality, bond durability and extremely low aldehydes emissions.
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Alma M. H. and Shraishi N. 1998. Preparation of polyurethane-like foams from NaOH-catalyzed liquefied wood [J]. Holz als Roh-und Werkstoff,56(4): 245–246.
Kurimoto Y., Doi S. and Tamura Y. 1999. Species effects on wood-liquefaction in polydric alcohols [J]. Holzforchung,53(6): 617–622.
Lin, L., Yao Y., Yoshioka, M.et al. 1997. Molecular weights and molecular weights distributions of liquefied wood obtained by acid-catalyzed phenolysis [J]. Journal of Applied Polymer Science,64(2): 351–357.
Lin, L., Yoshioka, M., Yao Y.et al. 1995. Preparation and properties of phenolated wood/phenol/formaldehyde cocondensed resin [J]. J. Appl. Poly. Sci.,58(8): 1297–1304.
Maldas, D., Shiraishi, N. and Harada, Y. 1997. Phenolic resol resin adhesives prepared from alkali-catalyzed liquefied phenolated wood and used to bond hardwood [J]. J. Adhesion Sci. Technol.,11(3): 305–316.
Marcos, A., Santana, E. and Melissa G.et al. 1996. Phenol-formaldehyde plywood adhesive resins prepared with liquefied bark of Black wattle [J]. Journal of wood chemistry and technology,16(1): 1–19.
Ono, H., Yamada T. 2000. Cellulosic materials-potential source for adhesives [J]. Chemistry and Adhesive,74: 44–49.
Pizza A. Wood Adhesives: Chemistry and Technology. New York: M. Dekker, c1983–c1989. 364p
Shiraishi, N. and Kishi, H. 1986. Wood-phenol adhesives prepared from carboxymethylated wood I [J]. J. Appl. Poly. Sci.,32(1): 3189–3209.
Shiraishi, N. and Kajita, H. Recent research on wood and wood-based materials [M]. London and New York: Elsevier Applied Science, 1993. 247p.
Tohmura, S., Inoue, A., Miyamoto, K.et al. 2003. Determination of acetaldehyde emission from wood-based materials applying the desiccator Mthod [J]. Settyaku Gakkaishi,39(5): 190–193.
Tsujimoto, N. 1984. Plasticization of wood [C]. In: Preprints for the 14th symposium on chemical processing of wood, Kyoto, 17–22.
Yao, Y., Yoshioka, M. and Shiraishi, N. 1995. Rigid polyurethane foams from combined liquefaction mixtures of wood and starch [J]. Mokuzai Gakkaishi,41(7): 659–668.
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Foundation item: The research was supported by Sino-Japanese Technical Cooperation Project (2-1-b) and the key technologies R & D Program for the 10th Five-Year Plan (325-11).
Biography: LI Gai-yun (1974-), female, Assistant professor in Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, P. R. China
Responsible editor: Zhu Hong
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Li, Gy., Qin, Tf., Tohmura, Si. et al. Preparation of phenol formaldehyde resin from phenolated wood. J. of For. Res. 15, 211–214 (2004). https://doi.org/10.1007/BF02911027
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DOI: https://doi.org/10.1007/BF02911027