Skip to main content
Log in

Preparation of phenol formaldehyde resin from phenolated wood

  • Published:
Journal of Forestry Research Aims and scope Submit manuscript

Abstract

The technique for preparing phenol formaldehyde resin from phenolated wood (PWF) and its characters were studied and analyzed. Poplar (Populus spp) wood meal was liquefied by phenol in the presence of sulfuric acid as a catalyst. After the liquefied products were cooled, alkaline catalyst and formaldehyde were added. The mixture was kept at (60±2)°C for 1h and then was heated to (85±2)°C for 1h. The influence of molar ratio of formaldehyde to phenol (F/P) was investigated. The results showed when the molar ratio of formaldehyde to phenol was over 1.8, the PWF adhesives had high bond quality, bond durability and extremely low aldehydes emissions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Alma M. H. and Shraishi N. 1998. Preparation of polyurethane-like foams from NaOH-catalyzed liquefied wood [J]. Holz als Roh-und Werkstoff,56(4): 245–246.

    Article  CAS  Google Scholar 

  • Kurimoto Y., Doi S. and Tamura Y. 1999. Species effects on wood-liquefaction in polydric alcohols [J]. Holzforchung,53(6): 617–622.

    Article  CAS  Google Scholar 

  • Lin, L., Yao Y., Yoshioka, M.et al. 1997. Molecular weights and molecular weights distributions of liquefied wood obtained by acid-catalyzed phenolysis [J]. Journal of Applied Polymer Science,64(2): 351–357.

    Article  CAS  Google Scholar 

  • Lin, L., Yoshioka, M., Yao Y.et al. 1995. Preparation and properties of phenolated wood/phenol/formaldehyde cocondensed resin [J]. J. Appl. Poly. Sci.,58(8): 1297–1304.

    Article  CAS  Google Scholar 

  • Maldas, D., Shiraishi, N. and Harada, Y. 1997. Phenolic resol resin adhesives prepared from alkali-catalyzed liquefied phenolated wood and used to bond hardwood [J]. J. Adhesion Sci. Technol.,11(3): 305–316.

    Article  CAS  Google Scholar 

  • Marcos, A., Santana, E. and Melissa G.et al. 1996. Phenol-formaldehyde plywood adhesive resins prepared with liquefied bark of Black wattle [J]. Journal of wood chemistry and technology,16(1): 1–19.

    Article  Google Scholar 

  • Ono, H., Yamada T. 2000. Cellulosic materials-potential source for adhesives [J]. Chemistry and Adhesive,74: 44–49.

    Google Scholar 

  • Pizza A. Wood Adhesives: Chemistry and Technology. New York: M. Dekker, c1983–c1989. 364p

    Google Scholar 

  • Shiraishi, N. and Kishi, H. 1986. Wood-phenol adhesives prepared from carboxymethylated wood I [J]. J. Appl. Poly. Sci.,32(1): 3189–3209.

    Article  CAS  Google Scholar 

  • Shiraishi, N. and Kajita, H. Recent research on wood and wood-based materials [M]. London and New York: Elsevier Applied Science, 1993. 247p.

    Google Scholar 

  • Tohmura, S., Inoue, A., Miyamoto, K.et al. 2003. Determination of acetaldehyde emission from wood-based materials applying the desiccator Mthod [J]. Settyaku Gakkaishi,39(5): 190–193.

    CAS  Google Scholar 

  • Tsujimoto, N. 1984. Plasticization of wood [C]. In: Preprints for the 14th symposium on chemical processing of wood, Kyoto, 17–22.

  • Yao, Y., Yoshioka, M. and Shiraishi, N. 1995. Rigid polyurethane foams from combined liquefaction mixtures of wood and starch [J]. Mokuzai Gakkaishi,41(7): 659–668.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Foundation item: The research was supported by Sino-Japanese Technical Cooperation Project (2-1-b) and the key technologies R & D Program for the 10th Five-Year Plan (325-11).

Biography: LI Gai-yun (1974-), female, Assistant professor in Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, P. R. China

Responsible editor: Zhu Hong

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, Gy., Qin, Tf., Tohmura, Si. et al. Preparation of phenol formaldehyde resin from phenolated wood. J. of For. Res. 15, 211–214 (2004). https://doi.org/10.1007/BF02911027

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02911027

Key words

CLC number

Document Code

Navigation