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Metal ion complexes of 2-acetylpyridine 3-(4-methyl)piperazinyl-thiosemicarbazone

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Summary

Metal complexes of stoichiometries, [M(HLppz4M)X2] and [M(Lppz4M)X], are formed from nickel(II) and copper(II) halides and 2-acetylpyridine 3-(4-methyl)piperizinylthiosemicarbazone, HLppz4M. The [M(Lppz4M)X] complexes involve tridentate N(pyridyl), N(azomethinyl) and S(thiolate) coordination with a halo ligand completing the bonding. Neutral HLppz4M coordinatesvia the two nitrogen donors. Spectral evidence indicates the presence of a thiol hydrogen in Hppz4M complexes, the first to be reported for a coordinated thiosemicarbazone.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, Illinois, USA

    Douglas X. West & Timothy J. Romack

  2. Department of Biological Sciences, Illinois State University, 61671, Normal, Illinois, USA

    Anthony E. Liberta

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  1. Douglas X. West
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  2. Timothy J. Romack
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  3. Anthony E. Liberta
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West, D.X., Romack, T.J. & Liberta, A.E. Metal ion complexes of 2-acetylpyridine 3-(4-methyl)piperazinyl-thiosemicarbazone. Transition Met. Chem. 17, 256–259 (1992). https://doi.org/10.1007/BF02910850

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  • DOI: https://doi.org/10.1007/BF02910850

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