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Preparation and electrochemistry of mixed nuclear complexes (OC)3 CrAreneCCo3(CO)9

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Summary

Four new mixed nuclear complexes of general formula (OC)3CrAreneCCo3(CO)9, prepared by reacting (OC)3-CrAreneHgAreneCr(Co)3 with HCCo3(CO)9, were characterized by elemental analyses, i.r. and u.v. spectra. The complexes were electrochemically oxidized in acetone solution by an irreversible multi-electron process at ambient temperature, but displayed a chemically reversible one-electron process at −25°C. The resulting stable cation was easily attacked by nucleophiles such as PPh3. The results indicated that low-temperature cyclic voltammetry(LTCV) in acetone might be a useful way to study (arene)tricarbonylchromium complexes.

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Authors and Affiliations

  1. Coordination Chemistry Institute, Nanjing University, 210008, Nanjing, P. R. China

    Shou-Heng Sun, Yi-Ming Yao, Hui-Zhen Zhu, Qing-Jin Meng & Xiao-Zeng You

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  1. Shou-Heng Sun
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  2. Yi-Ming Yao
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  3. Hui-Zhen Zhu
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  4. Qing-Jin Meng
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Sun, SH., Yao, YM., Zhu, HZ. et al. Preparation and electrochemistry of mixed nuclear complexes (OC)3 CrAreneCCo3(CO)9 . Transition Met. Chem. 17, 216–219 (1992). https://doi.org/10.1007/BF02910840

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  • DOI: https://doi.org/10.1007/BF02910840

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