Skip to main content
SpringerLink
Log in

Metal-containing monomers. Part 2*. Metal chelate monomers based on 1-phenyl-4-methylpent-4-en-1,3-dione

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

CoII, NiII, CuII, MnII, PdII, CrIII and FeIII chelate monomers based upon 1-phenyl-4-methylpent-4-en-1,3-dione have been synthesized by interaction of the metal salts with the sodium derivative of the ligand in water. The complexes were shown to have octahedral structure, with axial coordination of water. The method of dehydration of these compounds has been developed by the preparation of pyridine adducts with following their dryingin vacuo at 100°C. Graft polymerization of the monomers onto a polyethylene powder preirradiated in air has been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. E. Uflyand, A. G. Starikov, V. S. Savostyanov and A. D. Pomogailo,Transition Met. Chem.,16, 126 (1991).

    Article  CAS  Google Scholar 

  2. A. D. Pomogailo and V. S. Savostyanov,Metal-containing Monomers and Polymers on their Basis, Khimia, Moscow, 1988, p. 132.

    Google Scholar 

  3. I. E. Uflyand and A. D. Pomogailo,J. Coord. Chem., Sect. B, in press.

  4. K. H. Thiele and K. Jacob,Z. Anorg. Allg. Chem.,356, 195 (1968).

    Article  CAS  Google Scholar 

  5. G. N. Schrauser and R. J. Windgassen,J. Amer. Chem. Soc.,89, 1999 (1967).

    Article  Google Scholar 

  6. M. Naumberg, N. V. K. Duong and A. Graudemer,J. Organometal. Chem.,25, 231 (1970).

    Article  CAS  Google Scholar 

  7. V. T. Kalinnikov and Yu. V. Rakitin,Introduction in magnetochemistry, Nauka, Moscow, 1980, p. 320.

    Google Scholar 

  8. I. Terpinski,Spectrochim. Acta,36A, 621 (1980).

    CAS  Google Scholar 

  9. R. N. Holm and M. J. O'Connor,Progr. Inorg. Chem.,14, 241 (1971).

    Article  CAS  Google Scholar 

  10. G. I. Jardimalieva, A. D. Pomogailo, V. I. Ponomarev, L. O. Atovmyan, Yu. M. Shulga and A. G. Starikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1525 (1988).

  11. B. N. Figgis and I. Lewis,Progr. Inorg. Chem.,6, 37 (1964).

    Article  CAS  Google Scholar 

  12. R. Drago,Physical Methods in Chemistry, Vol. 2, W. B. Saunders, Philadelphia, P. A. 1977, p. 116.

    Google Scholar 

  13. C. K. Jorgensen,Adv. Chem. Phys.,5, 33 (1963).

    Article  Google Scholar 

  14. A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1984, 504 pp.

    Google Scholar 

  15. E. Kalalova, O. Populova, S. Stokrova and P. Stopka,Coll. Czech. Chem. Commun.,48, 2021 (1983).

    CAS  Google Scholar 

  16. J. C. Loehr, T. M. Loehr, A. G. Mauk and H. B. Gray,J. Amer. Chem. Soc.,102, 6992 (1980).

    Article  CAS  Google Scholar 

  17. N. S. Gill, R. N. Nuttall, D. E. Scaife and D. W. ScarpJ. Inorg. Nucl. Chem.,18, 79 (1961).

    Article  CAS  Google Scholar 

  18. C. K. Jorgensen,Absorption Spectra and Chemical Bonding in Complexes, Pergamon Press, Oxford, 1962, 320 pp.

    Google Scholar 

  19. V. S. Savostyanov, D. A. Kritskaya and A. N. Ponomarev,Chem. High Energies USSR,20, 153 (1986).

    CAS  Google Scholar 

  20. I. E. Uflyand, I. A. Ilchenko, V. N. Sheinker and A. V. Bulatov,Transition Met. Chem.,16, 293 (1991).

    Article  CAS  Google Scholar 

  21. H. Hirai, S. Komatsuzaki and N. Toshima,J. Macromol. Sci.,23A, 933 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, State Pedagogical Institute, Engelsa 33, 344 082, Rostov-on-Don, USSR

    Igor E. Uflyand, Irina A. Ilchenko, Andrei G. Starikov & Victor N. Sheinker

  2. Institute of Energetical Problems of Chemical Physics, Academy of Sciences, 142432, Chernogolovka, Moscow Region, USSR

    Vladimir S. Savostyanov

Authors
  1. Igor E. Uflyand
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Irina A. Ilchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Andrei G. Starikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Victor N. Sheinker
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Vladimir S. Savostyanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Part 1 see

TMC 2650

Rights and permissions

Reprints and permissions

About this article

Cite this article

Uflyand, I.E., Ilchenko, I.A., Starikov, A.G. et al. Metal-containing monomers. Part 2*. Metal chelate monomers based on 1-phenyl-4-methylpent-4-en-1,3-dione. Transition Met. Chem. 17, 458–463 (1992). https://doi.org/10.1007/BF02910732

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02910732

Keywords

Search

Navigation