Summary
The kinetics of complexation of MnII, CoII and ZnII by isocitric acid have been studied by the stopped flow method at 15,25 and 35°C, ionic strength 0.20 M (NaClO4) and pH range 4.50–6.35. Under these experimental conditions, one process is observed for each system within a few seconds. A mechanism is proposed to account for the observed behaviour, which is associated with participation of the OH group in complex formation. Activation energies are also reported.
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Canaviri, E.C., Féliz, M.R. & Capparelli, A.L. Kinetics of the complexation of manganese(II), cobalt(II) and zinc(II) with DL-isocitric acid. Transition Met. Chem. 17, 446–448 (1992). https://doi.org/10.1007/BF02910729
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DOI: https://doi.org/10.1007/BF02910729