Summary
Kinetics of aquation ofcis- andtrans-[Co(en)2NO2Cl]+ were investigated in aqueous mixtures of MeOH, EtOH,i-PrOH andt-BuOH at 298.1 K. The values of transfer functions corresponding to the transfer of reactant and activated complex from H2O to the solvent mixtures were calculated from kinetic measurements and from solubilities of the complex salt. The results of the analysis of solvent effect are discussed in terms of D and Id mechanisms.
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Grančičová, O., Stillhammerová, M. Kinetics of aquation ofcis- andtrans-chloro-nitrobis-(ethylene-diamine)cobalt(III) ion in binary aqueous mixtures. Transition Met. Chem. 17, 417–419 (1992). https://doi.org/10.1007/BF02910721
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DOI: https://doi.org/10.1007/BF02910721