Skip to main content
SpringerLink
Log in

Rearrangement and complexation of 5-substituted-1,3,4-thiadiazolidine-2-thiones with divalent transition metals

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The reactions of a variety of divalent transition metal ions with 3-methyl-5-(2-hydroxypheny)-, 3-methyl-5-(2-thienyl)-and 3-methyl-5-(2-furyl)-1,3,4-thiadiazolidine-2-thiones (htt, ttt and ftt, respectively) are accompanied by opening of the thiadiazolidine ring and rearrangement to the corresponding Schiff base (Hhts, Htts and Hfts, respectively) with the concomitant formation of complexes of the general formulae, [M(hts)] (M=Ni, Cu, Zn or Pd), [M(hts) (py)] (M=Ni, Cu), [Co(Hhts)hts)], and [ML2] (M=Ni, Cu, Zn or Cd); L=tts or fts). The complexes have been characterised by physico-chemical and spectroscopic methods. The fungitoxicities of the corresponding Schiff base metal complexes have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. C. Heugebaert and J. R. Willems,Tetrahedron,22, 913 (1966).

    Article  CAS  Google Scholar 

  2. M. Akbar Ali, S. E. Livingstone and D. J. Phillips,Inorg. Chim. Acta,7, 179 (1973).

    Article  Google Scholar 

  3. S. M. M. H. Majumder, M. Akbar Ali, F. E. Smith and K. M. M. Rahman,Polyhedron,9, 1017 (1990).

    Article  CAS  Google Scholar 

  4. M. Akbar Ali, P. K. Saha, M. Nazimuddin, S. M. M. H. Majumder and M. A. Khair, Unpublished results.

  5. L. F. Lindoy,Quart. Rev.,25, 379 (1971) and refs. therein.

    Article  CAS  Google Scholar 

  6. L. F. Lindoy and S. E. Livingstone,Inorg. Chim. Acta,1, 305 (1967).

    Google Scholar 

  7. H. Jadamus, Q. Fernandos and H. Freiser,J. Amer. Chem. Soc.,86, 3056 (1964).

    Article  CAS  Google Scholar 

  8. S. M. M. H. Majumder, M. Akbar Ali, F. E. Smith and M. A. U. Mridha,Polyhedron,7, 2183 (1988).

    Article  CAS  Google Scholar 

  9. M. Nazimuddin, M. Akbar Ali, F. E. Smith and M. A. U. Mridha,Transition Met. Chem., In Press.

  10. M. Akbar Ali, S. E. Livingstone and D. J. Phillips,Inorg. Chim. Acta,7, 553 (1973).

    Article  Google Scholar 

  11. D. A. Klayman, J. P. Scovill, J. F. Bartoservich and J. Bruce,J. Med. Chem.,26, 35 (1983).

    Article  CAS  Google Scholar 

  12. C. A. Rice, C. G. Benson and C. A. McAuliffe,Inorg. Chim. Acta,59, 33 (1982).

    Article  CAS  Google Scholar 

  13. A. Saxena, J. P. Tandon, K. C. Molloy and J. Zuckermann,Inorg. Chim. Acta,63, 71 (1982).

    Article  CAS  Google Scholar 

  14. M. F. Iskander, M. M. Mishirikey, L. El-Sayed and A. El-Toukhey,J. Inorg. Nucl. Chem.,41, 815 (1979).

    Article  CAS  Google Scholar 

  15. F. Goetz,J. Heterocyclic Chem.,5, 509 (1961).

    Article  Google Scholar 

  16. C. M. Harris and E. Sinn,J. Inorg. Nucl. Chem.,30, 2723 (1968).

    Article  CAS  Google Scholar 

  17. M. Akbar Ali and R. Bose,J. Inorg. Nucl. Chem.,39, 265 (1977); M. Akbar Ali, S. E. Livingstone and D. J. Phillips,Inorg. Chim. Acta,7, 179 (1973).

    Article  Google Scholar 

  18. S. Gou, X. You, Z. Zu, K. Yu and Z. Zhou,Polyhedron,9, 2981 (1990).

    Article  CAS  Google Scholar 

  19. M. Rahman, M. Akbar Ali and M. A. U. Mridha, unpublished results.

  20. D. X. West, C. S. Carlson, A. E. Liberta and J. P. Scovill,Transition Met. Chem.,15, 383 (1990); D. X. West, C. S. Carlson, C. P. Galloway, A. E. Liberta and C. R. Daniel,Transition Met. Chem.,15, 91 (1990).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Chittagong, Chittagong, Bangladesh

    Mohamed Nazimuddin, Khandker M. M. Rahman & Mizanur Rahman

  2. Department of Chemistry, University of Brunei Darussalam, BSB 3186, Brunei Darssalam

    Mohammad Akbar Ali

  3. Department of Botany, University of Chittagong, Chittagong, Bangladesh

    Mohammad A. Mridha

Authors
  1. Mohamed Nazimuddin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Khandker M. M. Rahman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mizanur Rahman
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Mohammad Akbar Ali
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Mohammad A. Mridha
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

TMC 2568

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nazimuddin, M., Rahman, K.M.M., Rahman, M. et al. Rearrangement and complexation of 5-substituted-1,3,4-thiadiazolidine-2-thiones with divalent transition metals. Transition Met. Chem. 17, 404–408 (1992). https://doi.org/10.1007/BF02910718

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02910718

Keywords

Search

Navigation