Summary
Some new low-spin hexacoordinated cyanonitrosyl complexes of Cr1 of the type [Cr(NO)(CN)2(L)2(H2)], where L is an aromatic aldehyde oxime or Mannich base, have been prepared by the interaction or K3[Cr(NO)(CN)5]· H2O with L in aqueous AcOH, and characterized by a range of physico-chemical techniques, I.r. data suggest that all the oxime derivatives and Mannich bases act as monodentate ligands by coordinating through the aromatic nitrogen.
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Maurya, R.C., Mishra, D.D., Jaiswal, S.K. et al. Synthesis and characterization of some novel cyanonitrosyl complexes of chromium(I) with Mannich bases, aromatic aldehyde oximes and syn-phenyl-2-pyridylketoxime. Transition Met. Chem. 17, 381–383 (1992). https://doi.org/10.1007/BF02910712
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DOI: https://doi.org/10.1007/BF02910712