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Complexation of silver nitrate with imidazolidine-2-thione and its derivatives

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Summary

The reaction of AgNO3 with imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz) and their derivatives yields complexes of stoichiometry [AgLNO3] (where L=Imt or Diaz and their derivatives). The C-2 resonances of the Diaz complexes were shifted more from the free ligand positions compared to the Imt complexes, suggesting that the former bind more strongly to Ag1 than the latter.

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References

  1. R.F. Uson, L. Laguna, J. Jimenez, M. P. Gomez and A. Sainz,J. Chem. Soc. Dalton Trans., 3457 (1989).

  2. F. A. Devillanova, G. Verani, L. P. Battaglia and A. B. Corradi,Transition Met. Chem.,5, 362 (1980).

    Article  CAS  Google Scholar 

  3. D. J. Williams, R. L. Junes and P. H. Poor,Inorg. Chim. Acta,144, 237 (1988).

    Article  CAS  Google Scholar 

  4. P. Castan and J. P. Laurent,Transition Met. Chem.,5, 154 (1980).

    Article  CAS  Google Scholar 

  5. R. U. Gadag and M. R. Gajendragad,Ind. J. Chem.,16A, 703 (1978).

    CAS  Google Scholar 

  6. R. Shunmugam and D. N. Sathyanarayana,J. Coord. Chem.,14, 27 (1985).

    Article  CAS  Google Scholar 

  7. A. A. Isab,J. Chem. Soc., Dalton Trans., 1046 (1986).

  8. F. A. Devillanova and G. Verani,Transition Met. Chem.,2, 120 (1977).

    Article  CAS  Google Scholar 

  9. F. J. Welcher,Organic Analytical Reagents, Vol. 4, Van Nostrand, New York, 1948.

    Google Scholar 

  10. M. J. Stiff,Analyst,97, 146 (1972).

    Article  CAS  Google Scholar 

  11. B. C. Bera and M. M. Chakrabarty,Anal. Chem.,38, 1419 (1966).

    Article  Google Scholar 

  12. W. O. Foye and J. R. Lo,J. Pharm. Sci.,61, 1209 (1972).

    Article  CAS  Google Scholar 

  13. H. Kohn, B. A. Kohn, M. L. Steenberg and J. P. Buckley,J. Med. Chem.,20, 158 (1977).

    Article  CAS  Google Scholar 

  14. Japanese Patent: JP7513318 (750203)

  15. Russian Patent: SU929662 (820523)

  16. B. Donnelly, T. C. Downie, R. Grzeskowiak, H. R. Hamburg and D. Short,Corros. Sci.,18, 109 (1978).

    CAS  Google Scholar 

  17. E. Beutler,Red Cell Metabolism: A manual of Biochemical Method, Grune and Stratton, New York, p 113, 1975.

    Google Scholar 

  18. N. Motohashi, I. Mori, Y. Sugiura and H. Tanaka,Chem. Pharm. Bull.,22, 654 (1974).

    CAS  Google Scholar 

  19. G. D. Thorn,Can. J. Chem.,33, 1278 (1955).

    Article  CAS  Google Scholar 

  20. L. Maier,Helv. Chim. Acta.,53, 1417 (1970).

    Article  CAS  Google Scholar 

  21. A. A. Isab,Polyhedron,8, 2823 (1989).

    Article  CAS  Google Scholar 

  22. A. A. Isab and M. S. Hussain,Polyhedron,4, 1683 (1985).

    Article  CAS  Google Scholar 

  23. A. A. Isab and M. S. Hussain,J. Coord. Chem.,15, 125 (1986).

    Article  CAS  Google Scholar 

  24. H. C. Ray and B. J. Sahoo,J. Indian Chem. Soc.,53, 646 (1976).

    Google Scholar 

  25. P. K. Das, P. P. De, A. K. Pande and D. Sen,Ind. J. Chem.,22A, 884 (1983).

    CAS  Google Scholar 

  26. R. Battistuzzi and G. Pyronel,Transition Met. Chem.,2, 87 (1977).

    Article  CAS  Google Scholar 

  27. A. A. Isab and H. Perzanowski,J. Coord. Chem.,21, 247 (1990).

    Article  CAS  Google Scholar 

  28. P. M. Henrichs, S. Sheard, J. J. H. Ackerman and G. E. Marciel,J. Amer. Chem. Soc.,101, 3222 (1979).

    Article  CAS  Google Scholar 

  29. M. D. Udupa, G. Henckel and B. Krebs,Inorg. Chim. Acta,18, 173 (1976).

    Article  CAS  Google Scholar 

  30. M. B. Ferrari, C. G. Fava and M. E. Vidoni Tani,Cryst. Struct. Commun.,10, 571 (1981).

    CAS  Google Scholar 

  31. L. D. Pettit, K. F. Siddiqui, H. Kozlowski and T. Kowalik,Inorg. Chim. Acta.,55, 87 (1981).

    Article  CAS  Google Scholar 

  32. A. A. Isab and C. F. Shaw III,J. Inorg. Biochem.,38, 95 (1989).

    Article  Google Scholar 

  33. E. S. Raper,Coord. Chem. Rev.,61, 115 (1985).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia

    Anvarhusein A. Isab

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  1. Anvarhusein A. Isab
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TMC 2670

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Isab, A.A. Complexation of silver nitrate with imidazolidine-2-thione and its derivatives. Transition Met. Chem. 17, 374–376 (1992). https://doi.org/10.1007/BF02910710

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  • DOI: https://doi.org/10.1007/BF02910710

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