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Bond valence parameters linearly dependent on the molybdenum oxidation states

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Chinese Science Bulletin

Abstract

Based on the available crystal data, a linear correlation betweenR 0, the bond valence parameter for a Mo-containing chemical bond, and the Mo oxidation staten was developed for the first time. Using the “universal” value of the parameterB = 0.037 nm, the linear equations ofR 0-n for Mo-X (X: O, S, N, Cl and F) bonds were established. The oxidation-state independent Mo-O bond valence parameters,R 0 = 0.18788 nm andB = 0.03046 nm, published recently have been shown to be a special case of the linearly correlated functions. Some bond valence sum calculations in compounds containing only Mo-O bonds using these parameters are presented.

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Authors and Affiliations

  1. Department of Chemistry, Institute of Physical Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, 361005, Xiamen, China

    Mingdan Chen, Zhaohui Zhou & Shengzhi Hu

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  1. Mingdan Chen
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  2. Zhaohui Zhou
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  3. Shengzhi Hu
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Correspondence to Shengzhi Hu.

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Chen, M., Zhou, Z. & Hu, S. Bond valence parameters linearly dependent on the molybdenum oxidation states. Chin. Sci. Bull. 47, 978–981 (2002). https://doi.org/10.1007/BF02907564

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  • DOI: https://doi.org/10.1007/BF02907564

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