Skip to main content
SpringerLink
Log in

Rheological phase synthesis and characterization of copper monosalicylate

  • Published:
Wuhan University Journal of Natural Sciences

Abstract

A new structural copper (II) monosalicylate, Cu(OC6H4C02)·H20, was synthesized by the rheological phase reaction method from salicylic acid and copper oxide in 1∶1 mole ratio. The structure was characterized by powder X-ray diffraction, IR and thermogravimetry. The Cu(OC6 H4 CC2)·H20 belongs to monoclinic system, with cell dimension:a=2.136 28(67),b=0. 657 84(22),c=l. 594 09(50) nm, β=108.434(25) ,V=2.125 28(83) nm3,Z=12, Dcalc=2.041 kg·L−1,D obs=2.003 kg·L−1. The crystal water was lost at 96–250°C. The determined magnetic moment and magnetic susceptibility were 1. 947 B. M. and 6. 546×10−6 (287. 20 K), respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Laine R M, Youngdahl K A, Kennish R A,et al. Superconducting Fibers from Organometallic Precursors, Part II: Chemistry and Low Temperature processing.J Mater Res, 1991,6: 895–907.

    Article  Google Scholar 

  2. Brumas V, Brumas B, Berthon G. Copper (II) Interactions with Nonsteroidal Antiinflammatory Agents, I: Salicylic Acid and Acetylsalicylic Acid.J Inorg Biochem, 1995,57(3): 191–207.

    Article  Google Scholar 

  3. Gerbeleu A P. Catalystic Activity of Copper(II) Hydroxo Salicylato Complexes.Zh Neorg Khim, 1992,37: 1830–1836 (Russ).

    Google Scholar 

  4. Miesel R, Weser U. Anticarcinogenic Reactivity of Copper-di-Schiff Bases with Superoxide Dismutase-Like Activity.Free Radical Res Commun, 1990,11: 39–51.

    Article  Google Scholar 

  5. Pavkovic S F. An IR Study of Benzoate Complexes.J Inorg Nucl Chem, 1971,33: 1475.

    Article  Google Scholar 

  6. Rissanen K, Valkonen J, Kokkonen P,et al. Structural and Thermal Studies on Salicylato Complexes of Divalent Manganese, Nickel, Copper and Zinc.Acta Chemica Scandinavica, 1987A41: 299–309.

    Article  Google Scholar 

  7. Yoshimura Y, Oki H, Tsuchiya R. Conditions for Crystallization of Various Copper(II) Complexes of Salicylic Acid in Aqueous Solution.Nippon Kagaku Kaishi, 1979,(4):502–508.

    Google Scholar 

  8. Sun J, Yuan L, Zhang K. The Thermal Decomposition of Zinc Monosalicylates.Thermochimca Acta, 1999,333: 141–145.

    Article  Google Scholar 

  9. Sun J, Yuan L, Zhang K,et al. The Thermal Decomposition Mechanism of Zinc Phthalate.Thermochimca Acta, 2000,343: 105–109.

    Article  Google Scholar 

  10. Sun J, Xie W, Yuan L,et al. Preparation and Luminescence Properties of Tb3+-Doped Zinc Salicylates.Mater Sci Eng B, 1999,64: 157–160.

    Article  Google Scholar 

  11. Lewandowski W, Baranska H. The Influence of Selected Metals on the Aromatic System of Salicylic Acid.Applied Spectroscopy, 1987,41: 976–980.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Molecular Sciences, Wuhan University, 430072, Wuhan, Hubei, China

    Yang Yi-yong, Li Liang-chao, Yuan Liang-jie, Sun Ju-tang & Zhang Ke-li

Authors
  1. Yang Yi-yong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Li Liang-chao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yuan Liang-jie
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sun Ju-tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zhang Ke-li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sun Ju-tang.

Additional information

Foundation item: Supported by The National Natural Science Foundation of China (29971024)

Biography: Yang Yi-you (1977-), male, Master, research direction: inorganic solid state chemistry and material chemistry.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yi-yong, Y., Liang-chao, L., Liang-jie, Y. et al. Rheological phase synthesis and characterization of copper monosalicylate. Wuhan Univ. J. Nat. Sci. 8, 425–427 (2003). https://doi.org/10.1007/BF02907224

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02907224

Key words

CLC number

Search

Navigation